12.2 原子吸收光谱仪.pdf

仪器分析 原子吸收光谱 ——仪器篇：光源 首都师范大学 仪器分析 首都师范大学 2 仪器分析 仪器设计思路 火焰 光源 棱镜 检测装置 首都师范大学 3 仪器分析 Statements from Sir Alan Walsh: Why are molecular spectra usually measured in absorption, and atomic spectra in emission? – There is apparently no good reason to disregard the absorption spectra of atoms. When a continuum source was used, a resolution of ~ 2 pm （0.002 nm ）would be required. The measurement of atomic absorption hence requires line radiation sources. The task of the monochromator is then merely to separate the line used for measurement from other Sir Alan Walsh lines emitted by the source. 1916-1998 “Application of atomic absorption spectrometry to analytical chemistry” 首都师范大学 仪器分析 空心阴极灯的发明 1955年Walsh发表的这篇论文解决了原子吸收光谱的光源问题； 随后Perkin-Elmer 和Varian公司推出了原子吸收商品仪器。 Ar ̶ + 首都师范大学 仪器分析 仪器结构流程 光源 原子化系统 单色器 检测器