高钛铝土矿高压水化法溶出试验研究.docVIP

doi： doi：10.3969/j.issn.1007-7545.2017.04.007 郑晓倩1,2，金会心1,2，魏国令1,2，肖冲1，吴宝珍1 （1.贵州大学 材料与冶金学院，贵阳 550025；2.贵州省冶金工程与过程节能重点实验室，贵阳550025） 摘要：分别采用高压水化法和拜耳法对某高钛铝土矿进行溶出，对比两种方法对Al2O3及TiO2溶出率的影响。研究了高压水化条件下溶出温度、苛性碱浓度、溶出时间以及石灰添加量对高钛铝土矿中Al2O3及TiO2溶出率的影响。结果表明，高压水化法更有利于提高Al2O3溶出率、降低TiO2溶出率，溶出效果优于拜耳法；高压水化法的最佳溶出条件为：溶出温度290 ℃、苛性碱浓度360 g/L、溶出时间60 min、石灰添加量8%，此条件下氧化铝的实际溶出率可达90.832%，TiO2的溶出率仅为4.108%。 关键词：高压水化法；高钛铝土矿；溶出条件 中图分类号：TF821 文献标志码：A 文章编号：1007-7545（2017）04-0000-00 Leaching Experimental Study of High Titanium Bauxite through High Pressure Hydrochemical Process ZHENG Xiao-qian1,2, JIN Hui-xin1,2, WEI Guo-ling1,2, XIAO Chong1, WU Bao-zhen1 (1. College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China; 2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang 550025, China) Abstract：High titanium bauxite was leached by high pressure hydrochemical process and Bayer process respectively. Leaching rates of Al2O3 and TiO2 of the above two processes were compared. Effects of leaching temperature, caustic concentration, leaching time, and lime dosage on leaching rates of Al2O3 and TiO2 were investigated in high pressure hydrochemical process. The results show that high pressure hydrochemical process is superiorer to Bayer process with higher leaching rate of Al2O3 and lower leaching rate of TiO2. The practical leaching rate of Al2O3 and TiO2 is 90.832% and 4.108% respectively in high pressure hydrochemical process under the optimum conditions including leaching temperature of 290 ℃, caustic concentration of 360 g/L, leaching time of 60 min, and lime dosage of 8%. Key words：high pressure hydration method; high titanium bauxite; dissolution conditions 高钛铝土矿占我国铝土矿总量的比例高达6%，其中贵州和云南的铝土矿中TiO2含量达到7%以上[1-2]。溶出过程中，如果没有有效的添加剂加入，含钛矿物可以使一水硬铝石型铝土矿几乎不能溶出，工业上一般在原矿桨中添加石灰来消除其影响，但是随着石灰添加量的增加，含钛矿物会与含钙成分反应生成钛酸钙和水合钛酸钙，这些成分通常会在换热器表面产生大量结疤，影响换热效率，造成能耗和氧化铝生产成本增大[3-5]，所以寻找开发利用复杂难处理型铝土矿的技术迫在眉睫。高压水化法是针对拜耳法处理高硅铝土矿容易造成大量Al2O3和Na2O损失而提出来的新方法，其机理是在高温(280~3