TU2无氧铜与铪的真空钎焊.pdf

上半月出版 TU2无氧铜与铪的真空钎焊 骆晓萌，王海龙，杨青松。邹坤 (江苏科技大学先进焊接技术省级重点实验室，江苏镇江212003) 摘要：使用BA972Cu钎料对TU2无氧铜与稀有金属铪(Hf)进行真空钎焊。借助金相显微镜、超景深显微镜、扫 描电镜、能谱分析、室温剪切试验等手段，分析了钎焊T艺参数(钎焊温度和保温时间)对钎焊接头组织及性能的影响。 结果表明：真空钎焊后获得的焊缝组织致密而连续。焊缝区均存在三个不同形貌的区域：铪侧的黑色区、中间花纹状 Ag-Cu共晶区和铜侧的峰峦状或鹅卵石状铜基园溶体区。随着钎焊温度升高和保温时间的延长，焊缝中峰峦状或鹅卵 石状组织越来越大，黑色区也越来越宽。而中间共晶区则减小。黑色带状区域中的Hf元素含量均大于4％．明显超过了 相图中Hf在Ag、Cu中的饱和固溶度．说明该区域中不可能仅存在铜或银与铪的二元同溶体组织。有可能存在三元固 溶体或含铪金属化合物。两种工艺参数均对接头的剪切破断应力影响不大。 关键词：铪；TU2无氧铜；真空钎焊；剪切破断应力；显微组织 中图分类号：TG454 文献标识码：A Vacuum ProcessofTU2 andHafnium Brazing Oxygen—freeCopper LUO Kun Xiaomeng，WANGHailong，YANGQingsong，ZOU (ProvincialKeyLabAdvancedWeldingTechnology,Jiangsu Abstract：Thevacuum ofTU2 andhafniumWasstudied filler brazingprocess oxygen-fleecopper byusingBA972Cu andshear effectsdifferent metal．ThroughSEM，EDS，metailographicmicroscopetest，the of process and microstluctureand ofthe were resultsshowthatthemain temperatureholdingtime)on propertiesjoints analyzed．The microstruetureof is ofthreemainareaswithdifferent blackareabeside mid brazingjointscomposed patterns-the nf,the areaof eutecficstructureandtheareaof basedsolidsolutionnealCu．Withtheincreaseof Ag-Cu copper brazing and theblackareaandtheareaof basedsolidsolutionbecome the time，both wider，however temperatureholding copper midareaof eutecticstructurebecomenarrower．Intheblackarea,Hfcontentisaboutover is Ag—Cu 4％，which