大学化学科学出版社习题解答.pptVIP

第1章习题 第一页，编辑于星期六：二点 五十八分。 解：查表有： 2 NH3 (g) = N2(g) + 3 H2(g) ΔfG?m(298.15K)/( kJ·mol-1) -16.45 0 0 ΔfH?m(298.15K)/( kJ·mol-1) -46.11 0 0 S?m(298.15K)/(J·mol-1·K-1) 192.45 191.50 130.684 (1)ΔrG?m(298.15K) = 1×0 + 3×0 - 2×(-16.45) = 32.9 kJ·mol-1 ΔrH?m(298.15K) = 1×0 + 3×0 - 2×(-46.11) = 92.22 kJ·mol-1 ΔrS?m(298.15K) = 1×191.50 + 3×130.684 - 2×192.45 = 198.652 J·mol-1·K-1 ΔrG?