电化学除铁用于建筑物的供水系统.docVIP

电化学除铁用于建筑物的供水系统 目录 TOC \o 1-9 \h \z \u 目录 1 正文 1 文1：电化学除铁用于建筑物的供水系统 1 1　试验装置和方法 3 2 　结果和讨论 3 3 结论 7 文2：铁质活性滤膜接触氧化除铁原理 7 一、前言 7 二、新滤料的除铁作用 8 三、滤料的成熟过程 10 四、铁质活性滤膜的化学组成及其催化的基本特征 12 五、成熟滤层的接触氧化除铁速率 14 六、几点结论 17 参考文摘引言： 18 原创性声明（模板） 19 文章致谢（模板） 19 正文 电化学除铁用于建筑物的供水系统 文1：电化学除铁用于建筑物的供水系统 Iron Removal by Electrochemical Method for Water Supply System of Buildings Abstract：A new electrochemical technology of water treatment for iron removal was propose d,which did not need any chemical agent and had no secondary perfo rmance mechanism was electrolysis. Fe2+ was oxidized to Fe3+ by nascent oxygen and dissolved oxygen produced by anodic reaction (with dimeionally s table anodes),the Fe3+ was hydrolyzed to ferric hydroxide,and then the hyd rolysate was filtrated off by sand-bed pH increased due to the increas e of OH- formed by cathode reaction, the oxidation rate was ferr ic hydrocolloid particles were flocculated into much bigger flocs by small bubbl es produced during electrolysis process,so that the condition of filtration was higher the electrical charge passed per litter of water the high er the ability of iron removal,but the lower the current total ir on content was decreased from mg/L to≤/L,under the test conditio of current deity /cm2,electrical charge per litter of water≥50 C/L (H2O),and single-pass operation,with quartz sand media circulating treatment,the rusty brown water in tank was cleaned efficiently,and the electri c power coumption was≤(kW·h)/m3 (H2O).The test result showed that the circulating treatment is applicable to water supply system of urban buildings. Keywords: water treatment; iron removal; electrochemistry 目前，城市建筑物中的供水系统由于管道锈蚀等原因，流出的自来水往往因含铁量高而发黄、发浑且带铁腥味，给人们的生活和工作带来极大的困扰，即使采用市售的各类净水器也难以解决问题，其中滤芯会很快失效；若拆除旧管道重新安装则费用高且施工困难。 传统的除铁水处理采用的是氧化加过滤的方法，但曝气和加药设备不适用于水箱系统。也有用溶解性铁或铝电极电解水除铁的报道，但这会增加水中金属离子和形成大量絮状沉淀物，增加后续处理的负担。作者采用不溶性的金属阳极电解，利用电化学反应产生的溶解氧将水中二价铁氧化成三价铁，不需任何化学药剂且无二次污染，可以根据水中含铁量调节供电量，使处理水达到自来水水质标准。