电子级异丙醇制备技术-三塔共沸精馏及双塔共沸精馏流程模拟对比.pdfVIP

Purification of Electronic-Grade Isopropyl Alcohol Team Social Distillation Project Background  Electronic grade solvents are used at various steps within semi- conductor processing  Purity of solvents is important for product quality  Isopropyl alcohol is used in the final step in semi-conductor production in pure form Project Goals  Feed to be purified contains organic and metal components  Goal specified from industry partner is to separate 99.999% pure isopropyl alcohol  Implement recycle streams for additive solvents to reduce materials costs and chemical waste Previous Work  Rachel Meeuwsen’s Honor’s Thesis has been the foundation of our project  Primary method of separation is distillation and molecular sieves  Solvents used and not recycled -- DMSO and cyclopentane  Final purity of isopropyl alcohol was 99.95% Research for Azeotropic Distillation  Alternative chemical additives for azeotropic distillation processes  Ethylene Glycol for the removal of Isopropyl Acetate as an alternative for DMSO US Patent 4,826,576  Methyl ethyl ketone, 2,4-Dimethyl Pentane, 2-Pyrrolidinone for the removal of ethanol as alternatives for Cyclopentane, all chemicals create a solution with relative volatility of 1.45 US Patent 5,338,411  Parameters for evaluating chemical performance  Removal efficiency  Recyclability  Flowrate requirements and overall cost  Environmental impact and waste treatment requirements PFD Original Column Design with recycle/purification loops PFD Two Column Design with recycle/purification loops HYSYS Modeling Original Design- Completed by Rachel Meeuwsen HYSYS Modeling Original Design with purification/recycle loops HYSYS Modeling Two Column Design with recycle/purification loops Metal Particle Remov