Agilent Model 355Sulfur Chemiluminescence Detector (SCD) Sulfur Analysis Versus the Copper Strip Corrosion Test 说明书用户手册.PDF
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Agilent Model 355Sulfur
Chemiluminescence Detector (SCD):
Sulfur Analysis Versus the Copper
Strip Corrosion Test
Technical Overview
Introduction copper strip corrosion test. This occurs when a
masking agent is present in the LPG. Masking
The copper strip corrosion test (ASTM 1838) is agents are polar compounds that preferentially
commonly used as a product specification for chemisorb to the copper surface, preventing the
liquid petroleum gases (LPGs). The test is designed formation of the copper tarnish. Amines, glycol
to detect the presence of components that may be amines, and other compounds such as sulfolane
corrosive to copper and copper-alloy fittings that are known to have this effect. Mercaptans can
come into contact with the product. While the test also inhibit copper tarnish. The following
is very simple to perform, its interpretation can be chromatogram illustrates this masking effect. [3]
subjective. Furthermore, the test can produce erro-
neous results and it does not indicate the actual
cause of corrosion, although it is generally assumed Hydrogen sulfide
to be due to sulfur compounds.
Sulfolane
Some situations where copper strip corrosion does
not perform satisfactorily are as follows. While the
presence of carbonyl sulfide does not cause corro-
sion in LPG systems, corrosive hydrogen sulfide is 0 40 80 120 160 200 240 280
formed upon hydrolysis of carbonyl sulfide. Thus,
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