AGILENT The Analysis of Trace Contaminants in High Purity Ethylene and Propylene Using GC MS Application Note说明书用户手册.PDF

The Analysis of Trace Contaminants in High Purity Ethylene and Propylene Using GC/MS Agilent Technologies/Wasson ECE Monomer Analyzer Application Authors (thermal conductivity detection), the Introduction use of GC/MSD demonstrates com- Fred Feyerherm parable performance with respect to For the polymer industry, the 119 Forest Cove Dr. linearity and repeatability: for exam- purity of ethylene and propylene Kingwood, TX 77339 ple, for mercaptans and sulfides monomer feedstocks is a high (40–100 ppb) in the ethylene assay, priority. Trace contaminants at John Wasson correlation coefficients for calibra- the part-per-billion (ppb) con- Wasson-ECE Instrumentation tion curves range from 0.992 to 1.000 centration levels can affect 101 Rome Court and relative standard deviations yields dramatically by altering Fort Collins, Colorado 80524 range from 1.95% to 9.31% RSD. subsequent polymer properties Compared to GC/FID for the range of and characteristics. Additionally, contaminant analytes studied here, some trace impurities can irre- Abstract the sensitivity is increased 50-fold; versibly poison reactor catalysts. compared to GC/TCD, the sensitivity The competitive marketing A new product (Application 4