(8261)--硅酸盐水泥水化产物微纳结构的原位研究.pdfVIP

硅酸盐水泥水化产物微纳结构的原位研究 摘 要：采用BSE-Raman 原位表征了硅酸盐水泥水化产物的Raman 光谱和空间分布。结果表明：BSE-Raman 能够原位获取 1 2 3 水化硅酸钙(C–S–H) 中硅氧四面体链Q 、Q 、Q 的结构信息。不同形貌组分的原位Raman 光谱均由多种水化产物的Raman 特征峰组成，即水泥水化产物在纳米尺寸存在混合现象。其中，占比最大的绒球状骨架主要由 C–S–H 和钙矾石(AFt)组成。 BSE-Raman 可快速、原位、精确识别不同的物相，在水泥基材料微结构表征方面具有广阔前景。 In-situ Study on Micro-Nano Structure of Portland Cement Hydration Products ZHU Zheyu, WANG Zhongping, ZHOU Yue, CHEN Yuting, WU Kai (School of Materials Science and Engineering, Tongji University, Shanghai 201804, China) Abstract: BSE-Raman was used to investigate in-situ Raman spectra of hydration products and their spatial distribution profiles. It 1 2 3 was found that the in-situ structural information of the silicon-oxygen tetrahedral Q , Q and Q chains of C–S–H could be readily obtained, while the hydration products could be accurately identified. All the hydration products with different morphologies exhibited multiple characteristic peaks of chemical bonds of the hydration products. Therefore, it was concluded that the cement hydration products were mixed at nanometer scale. The pom-shaped hydration product had a skeleton consisting of C–S–H and ettringite. Due to its ability of quick and accurate in-situ identification of different phases, BSE-Raman has broad prospects in the microstructural characterization of cement-based materials. Keywords: Portland cement; Raman spectra; in-situ; calcium silicate hydrates; ettringite 硅酸盐水泥广泛应用于结构与功能材料中，其 结构，发现C–S–H 与CH 混合的微结构。Wei 等[6] [1–3] 水化产物结构和组成决定了水泥基材料的性能 。 采用扫描探针显微镜(SPM)和纳米压痕系统，研究 水泥水化产物可划分为外部水化产物(Op)和内部水