带有磷酸化侧新型氟化聚合物.pdfVIP

J Polym Res (2011) 18:1409 1416 10.1007/s10965 010 9545 7 ORIGINAL PAPER Novel fluorinated polymers bearing phosphonated side chains: synthesis, characterization and properties Yuanqin Zhu Haihua Chen Chuanglong He Received: 6 August 2010 /Accepted: 30 November 2010 /Published online: 14 December 2010 # Science+Business Media B.V. 2010 A new class of aryl trifluorovinyl ether monomers Fluoropolymers . Polyelectrolytes . containing phosphonated oligo(ethylene oxide) units were Phosphonate . Oligo(ethylene oxide) designed and synthesized. Novel fluorinated polymers con- taining perfluorocyclobutane and phosphonic acid moieties were prepared from these monomers via the thermal cyclo- Introduction polymerization and hydrolysis reaction. The structures of these monomers and polymers were characterized by nuclear The proton exchange membrane (PEM) is a vital compo- ma ic resonance spectroscopy and fourier transform nent of hydrogen-oxygen fuel cells which are drawing spectroscopy. The thermal properties of these polymers were reased attention for their using as alternative power evaluated with differential scanning calorimetry and thermo- sources [1]. So far, many hydrocarbon polymers and gravimetric ysis. The 5% weight loss of these polymers partially fluorinated polymers have been considered as ® was in range of 258–270 °C in nitrogen, but no glass transition alternatives for Nafion . Compared with hydrocarbon temperatures were detected. The polymers showed good polymers, partially fluorinated polymers are attractive solubility in organic solvents such as dimethyl