硫化锌纳米材料的制备、掺杂与发光性能的研究的中期报告.docxVIP

硫化锌纳米材料的制备、掺杂与发光性能的研究的中期报告 （英文版） Mid-term Report on the Preparation, Doping and Luminescence Performance of Zinc Sulfide Nanomaterials Introduction Zinc sulfide (ZnS) is an important semiconductor material with potential applications in optoelectronics, catalysis, and biomedicine. Its photocatalytic activity and excellent optical properties make it a promising luminescent material. In recent years, ZnS nanomaterials have attracted increasing attention due to their enhanced properties compared to bulk ZnS, including a larger surface area and quantum confinement effects. The goal of this research is to prepare ZnS nanoparticles, dope them with different elements, and investigate their luminescence properties. Methods ZnS nanoparticles were prepared by a simple chemical precipitation method. Zinc acetate and thiourea were used as the precursors. The reaction was carried out in aqueous solution at room temperature, followed by centrifugation and washing. The resulting ZnS nanoparticles were then doped with different elements using a similar method. The dopants used in this study were Mn, Cu, and Ag. Results The prepared ZnS nanoparticles were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. The XRD results showed that the ZnS nanoparticles had a cubic structure. TEM images confirmed the formation of well-dispersed nanoparticles with an average size of 10-20 nm. The PL spectra showed a broad emission band with a peak around 392 nm, which corresponds to the band gap emission of ZnS. Doping of the ZnS nanoparticles with Mn resulted in a blue shift of the PL spectra, indicating energy transfer from Mn to ZnS. Doping with Cu and Ag resulted in a red shift of the PL spectra, indicating the formation of surface defects. The intensity of the PL spectra was found to increase with the doping concentration up to a certain point, after which it decreased. Discussion The results of this study demonstrate th