参考学习资料流体输配管网 1_A Diffusion Model of Binary Systems Controlled by Chemical Potential Gradient.pdf

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JournalofCastingMaterialsEngineeringVol.6No.2(2022)39–44

/10.7494/jcme.209

ADiffusionModelofBinarySystems

ControlledbyChemicalPotentialGradient

MarekWróbel,AndriyBurbelko

AGHUniversityofScienceandTechnology,FacultyofFoundryEngineering,al.A.Mickiewicza30,30-059Krakow

e-mail:marek.wrobel@.pl

accordingtotheCreativeCommonsCC-BY4.0Licenserequiringthattheoriginalworkhasbeenproperlycited.

Received:31October2021/Accepted:21March2022/Publishedonline:27April2022.

ThisarticleispublishedwithopenaccessatAGHUniversityofScienceandTechnologyPress.

Abstract

Thepaperpresentsamodelofdiffusioninasinglephasewithchemicalpotentialgradientasthedrivingforceoftheprocess.

Fick’slawsarestrictlyempiricalandtheassumptionthattheconcentrationgradientsarethedrivingforcesofdiffusionisfarfrom

precise.Instead,thegradientofchemicalpotentialμofcomponentiistherealdrivingforce.Thematterofgoverningequations

ofmodelsthatincorporatethisapproachwillberaisedanddiscussedinthisarticle.Oneofmoreimportantfeaturesistheability

toacquireresultswherediffusionagainsttheconcentrationgradientmayoccur.ThepresentedmodelusestheFiniteDifference

Method(FDM)andemploystheCALPHADmethodtoobtainchemicalpotentials.Thecalculationsofchemicalpotentialarecarried

outforinstantconditions–temperatureandcomposition–intheentiretaskdomainbyThermo-CalcviaaTQ-Interface.Thenthe

heterogeneityofchemicalpotentialsistranslatedintomasstransferforeachindividualelement.Calculationsoftwomodelling

tasksforone-dimensiondiffusionfieldwerecarriedout.First:isothermalconditionswithlinearinitialcompositi

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参考学习资料 流体输配管网 1_A Diffusion Model of Binary Systems Controlled by Chemical Potential Gradient.pdf