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热电材料中硅化物性能与应用研究.pdfVIP

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热电材料中硅化物性能与应用研究.pdf

    Thermoelectric

    PropertiesofSilicides

    CroninB.Vining23.1Abstract

    Consultant23.2Introduction

    23.3EvaluationCriteria

    23.4PropertiesofMetalSilicides

    .

    AlkaliandAlkalineEarthSilicidesRareEarthSilicidesGroups

    IVBandVBSilicidesCr,Mo,andWSilicidesMnandRe

    SilicidesFe,Ru,and0sSilicidesCo,Rh,andIrSilicidesNi,

    Pd,andPtSilicides

    23.5Summary

    References

    23.1Abstract

    ForthemostcommonlyusedthermoelectricmaterialsPbTe,SiGe),theconductionand

    valencebandsarederivedfroms-andp-orbitals.Butmostthermocouplewirematerials(chromel,

    consistofalloyswithpartiallyfilledd-bands,becausevaluesaremuch

    largerford-bandalloysthanformetalswithfilledoremptyd-bands(suchasCuorNa,respec-

    tively).Certainsilicidesemiconductorsthatexhibitd-bandcharacterinthevalencecon-

    ductionbandmaybeabletocombinethe

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