(2.4.3)--核外电子构造原理和电子组态.pdfVIP

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(2.4.3)--核外电子构造原理和电子组态.pdf

2.4.3Thebuildingupprinciple

andtheelectronicconfigurations

I.Thebuildingupprinciple(forthegroundstate)

a.Pauliexclusionprinciple.

Everyorbitalmaycontainonlytwoelectronsof

oppositespins.

b.Theprincipleofminimumenergy.

WhilstbeingcompatiblewiththePauliprinciple,

electronsoccupytheorbitalwiththelowestenergyfirst.

Formulti-electronatoms:

Theenergylevelcanbeestimatedbyn+0.7l.(G.X.Xuproposed.)

1s2s2p3s3p3d4s4p4d4f

1.02.02.73.03.7

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