(2.5.2)--原子光谱项和谱项符号及推导.pdfVIP

2.5.2Atomictermandtermsymbol

Asetofequal-energyatomicstatesthatarisefromthesame

electronconfigurationandthathavesamevalueofLandthe

sameSvalueconstitutesanatomicterm.

Termsymbol:2S+1L

Eachtermconsistsof(2L+1)(2S+1)atomicstates.(spin-

orbitinteractionneglected)

D:L=2,S=1

2P:L=1,S=1/2

2.5.3DerivationofAtomicterm

a.ConfigurationsofCompletelyfilledsubshells

M=m=0--S=

Sisi

M=m=0--L=

Lii