(2.4.8)--核外电子构造原理和电子组态.pptVIP

2.4.3Thebuildingupprincipleandtheelectronicconfigurations

I.Thebuildingupprinciple(forthegroundstate)a.Pauliexclusionprinciple.Everyorbitalmaycontainonlytwoelectronsofoppositespins.b.Theprincipleofminimumenergy.WhilstbeingcompatiblewiththePauliprinciple,electronsoccupytheorbitalwiththelowestenergyfirst.

Formulti-electronatoms:Theenergylevelcanbeestimatedbyn+0.7l.(G.X.Xuproposed.)1s2s2p3s3p3d4s4p4d4f1.02.02.73.03.74.44.04.75.46.15s5p5d5f6s6p6d6f??5.05.76.47.16.06.77.48.1??Therefore,thesequenceoftheatomicorbitals