2A12_1Cr11Ni2W2MoV电偶腐蚀行为与防腐设计研究.docxVIP

《热加工工艺

《热加工工艺》2022年5月第51卷第10期

2A12/lCrllNi2W2MoV电偶腐蚀行为

与防腐设计研究

龙开琳\朱化强2

(1.贵阳产业技术研究院，贵州贵阳550081;2.贵州师范大学物理与电子科学学院.，贵州贵阳550025)

摘要：采用电化学方法、酸性盐雾试验和周期浸润试验研究了几种2A12/lCrllNi2W2MoV电偶对的电偶腐蚀行为。利用SEM.EDS分别对试样进行表面形貌观察、元素分析及腐蚀机制研究，并依据电偶腐蚀敏感性和耐腐蚀能力合理设计电偶防腐方案。结果表明，电化学信息能预测电偶对电偶腐蚀敏感性，可作为实际应用中选材的依据，各电偶对

中2A12-SAA/CdP电偶腐蚀敏感性最显著；2A12铝合金表面硫酸阳极化可以提高试件耐腐蚀能力且有效降低电偶腐蚀速率;各电偶对腐蚀的机理是电偶腐蚀与缝隙腐蚀协同作用的结果；2A12-SAA试件喷涂缓蚀剂后防护效果明显，能有效抑制电偶腐蚀。

关键词：2A12铝合金；电偶腐蚀；腐蚀敏感性；镀层；腐蚀电流密度

DOI:10.14158/j.cnki.1001-3814中图分类号:TG178 文献标识码：A 文章编号：1001-3814(2022)10-0045-06

StudyonGalvanicCorrosionBehaviorandAnticorrosionDesign

of2A12/lCrllNi2W2MoV

LONGKailin1,ZHUHuaqiang2

(1.GuiyangIndustrialTechnologyInstitute,Guiyang550081,China;2.SchoolofPhysicsandElectronicScience,GuizhouNormalUniversity,Guiyang550025,China)

Abstract:Thegalvaniccorrosionbehaviorofseveral2A12/lCrllNi2W2MoVgalvaniccoupleswasstudiedbyelectrochemicalmethod,acidsaltspraytestandperiodicinfiltrationtest.Thesurfacemorphology,elementanalysisandcorrosionmechanismofthesampleswereanalyzedbySEMandEDS,respectively.Basedonthecorrosionsensitivityandcorrosionresistanceofgalvaniccouples,areasonableanti-corrosionschemeforthegalvaniccouplewasdesigned.Theresultsshowthattheelectrochemicalinformationcanpredictthecorrosionsensitivityofgalvaniccouples,whichcanbeusedasabasisformaterialselection.Amongallthegalvaniccouples,thecoupleof2A12-SAA/CdPhasthemostsignificantcorrosionsensitivity.Sulfuricacidanodizationonthesurfaceof2A12aluminumalloycanimprovethecorrosionresistanceofthespecimenandeffectivelyreducethegalvaniccorrosionrate.Thecorrosionmechanismistheresultofthesynergisticeffectofgalvanicandcrevicecorrosion.Theprotectiveeffectof2A12-SAAcouplesprayedwithcorrosioninhibitorisobvious,whichcaneffectivelyinhibitthegalvaniccorrosion.

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