U-600工艺中催化剂及化学品使用说明.pdfVIP

1.5.1Catalyst

ParaTolueneSulfonicAcid(pTSA)isusedasacatalystinU-600forthe

dehydrationofMBAintoStyreneProduct.

Itsdeliveryformisinliquidform,dilutedinwater(pTSA/water65/35%wt).

Thecatalystisconsumedintheprocessandnoregenerationisrequired.

PTSAconcentration(purecomponent)shallbe150ppmwtintotalliquidto

reactorR-1610.Estimatedconsumptionisasfollows(initsdeliveryform,i.e.:

takingintoaccountdilutedwater):

Expectedum

consumptionconsumption

32.0kg/h38.4kg/h

256t/y307t/y

Forchemicalandphysicalproperties,refertocorrespondingMaterialSafetyData

SheetinOperatingInstructionManual.

MandatoryvendorsareCromogeniacompany(CealPTS)orStepancompany.

1.5.2Chemicals

•4-tert-Butylcatechol(TBC):

4-tert-Butylcatechol(TBC)isusedasastyrenepolymerizationinhibitorinU-600.

Itsdeliveryformisinliquidform,dilutedinwater(TBC/water:85/15%wt).

TBCconcentration(purecomponent)shallbe10ppmwtinstreamswheretobe

injected,i.e.:overheadgasofcolumns(C-1620,C-1640andC-1650),column

vacuumsystems(PA-1620,PA-1640andPA-1650)andstyrenemonomerproduct

upstreamstorage.

EstimatedconsumptionofTBCisasfollows(initsdeliveryform,i.e.:takinginto

accountdilutedwater):

1.5.1催化剂

对甲苯磺酸(pTSA)在U‑600中用作催化剂，用于将MBA脱水为苯乙烯产品。

其交付形式为液体形式，用水稀释（pTSA/水65/35%wt）。

催化剂在此过程中被消耗，无需再生。

PTSA浓度（纯组分）在反应器R‑1610