高温液态金属铝腐蚀锰铝青铜表面复合界面的研究.docxVIP

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第54卷 第12期

2025年6月

热加工工艺

HotWorkingTechnology

ISSN1001-3814CN61-1133/TG

DOI:10.14158/j.cnki.1001-3814.试验与研究 rjggy@

试验与研究

高温液态金属铝腐蚀锰铝青铜表面复合界面的研究

张德寿1,巫林1,刘洋赈1,高希瑞2,郑宝超1

(1.暨南大学化学与材料学院先进耐磨蚀及功能材料研究院,广东广州510632;2.上海交通职业技术学院汽车工程学院,上海219000)

摘要院利用液态金属铝腐蚀锰铝青铜表面形成Cu-Al互扩散层遥通过正交试验在腐蚀温度720℃尧4wt%KF助镀剂尧10min腐蚀时间下获得最佳的铝铜复合式界面扩散层遥通过XRD尧SEM尧EDS尧XPS以及纳米压痕仪等对复合界面扩散层的形貌尧成分和硬韧性进行分析和表征遥结果表明院腐蚀界面由均匀的腐蚀层构成袁界面为冶金结合界面袁互扩散层的析出相以CuAl2相为主袁厚度达120滋m袁其硬度比锰铝青铜基体高2倍遥腐蚀扩散层兼具较好的硬韧性遥

关键词院液态金属腐蚀曰助镀剂曰界面腐蚀曰扩散层曰硬韧性

中图分类号院TG174 文献标识码院A 文章编号院1001-3814(2025)12-0022-07

StudyonCompositeInterfacesonSurfaceofManganese-Aluminum-BronzeCorrodedbyHigh-temperatureLiquidMetalAluminum

ZHANGDeshou1,WULin1,LIUYangzhen1,GAOXirui2,ZHENGBaochao1

(1.InstituteofAdvancedAbrasionResistanceandFunctionalMaterials,CollegeofChemistryandMaterials,JinanUniversity,Guangzhou510632,China;2.SchoolofAutomotiveEngineering,ShanghaiCommunicationsPolytechnic,Shanghai219000,China)

Abstract院ACu-AlinterdiffusionlayerwasformedonthesurfaceofMn-Albronzecorrodedbyliquidmetalaluminum.

Thebestaluminum-coppercompositeinterfacialdiffusionlayerwasobtainedatthecorrosiontemperatureof720℃,4wt%KFplatingaidand10mincorrosiontimebyorthogonalexperiment.Themorphology,compositionandtoughnessofthecompositeinterfacialdiffusionlayerwereanalyzedandcharacterizedbyXRD,SEM,EDS,XPSandnano-indentationinstrument.Theresultsshowthatthecorrosioninterfaceiscomposedofuniformcorrosionlayer,theinterfaceismetallurgicalbondinginterface,andtheprecipitatedphaseoftheinterdiffusionlayerismainlyCuAl2phase.Thethicknesscanreach120滋m,thehardnessis2timeshigherthanthatofthemanganesealuminumbronzematrix,andthecorrosiondiffusionlayerhasgoodhardnessandtoughness.

Keywords院liquidmetalcorrosion;platingaid;inte