有机化学问题与计算汇编.pdfVIP

哪种化合物既是手性又是酸性的？

D(2008.6)

2.完全燃烧时，发现1摩尔有机化合物X需要2.5摩尔分子氧。

哪些化合物可能是X？

1C2H5OH2

C2H23CH3

CHO2,

3(2008.6)

3.山梨醇是一种天然存在的具有甜味的化合物。食品工业常用它作为蔗糖的替代品。

该图显示了其结构。

山梨醇中存在多少个手性？

A1B2C3D4

D(2008.11)

4.

本题相关数据可在中找到。

乙酸乙酯可以通过以下反应由乙酸和乙醇制得。

CH2OH+CO2H⇌CO2CH2CH3+H2O

将乙醇（30g）和乙酸（30g）一起回流加热，得到22g乙酸乙酯。

酯的产率？

A25％B38％C50％D77％

Whichcompoundisbothchiralandacidic?

D(2008.6)

2.

Forcompletecombustion,1molofanorganiccompoundXwasfoundtorequire

2.5molofmolecularoxygen.

WhichcompoundscouldbeX?

1C2H5OH

2C2H2

3CHO

2,3(2008.6)

3.

Sorbitolisanaturally-occurringcompoundwithasweettaste.Itisoftenusedasa

substituteforsucrosebythefoodindustry.

Thediagramshowsitsstructure.

Howmanychiralcentresarepresentinsorbitol?

A1B2C3D4

D(2008.11)

4.

UseoftheDataBookletisrelevanttothisquestion.

Ethylethanoatecanbeobtainedfromethanoicacidandethanolbythefollowing

reaction.

CH2OH+CO2H⇌CO2CH2CH3+H2O

Ethanol(30g)andethanoicacid(30g)areheatedunderrefluxtogether,and22g

ofethylethanoateareobtained.

Whatistheyieldoftheester?

A25%B38%C50%D77%

5.下列哪项适合用于灭火器？1CBrF32CH3(CH2)5CH2Br3HCl

1(2008.11)6。

5.

Whichofthefollowingwouldbesuitableforuseinafireextinguisher?

1CBrF3

2CH3(CH2)5CH2Br