导电剂对锂离子电池性能的影响_1000000757625111.pdfVIP

导电剂对锂离子电池性能的影响/刘露等·267·

导电剂对锂离子电池性能的影响

刘露,戴永年,姚耀春

(昆明理工大学材料与冶金工程学院,昆明650093)

摘要综述了锂离子电池电极中添加不同的导电剂对电池性能的影响。用碳黑作为导电剂能明显改善电池的

性能;采用具有特殊形状的碳丝则有更好的效果;采用电导率高的金属作为导电剂,可以使电池在大电流充放电时保

持高容量和高循环效率;导电剂的含量对电池的性能也有明显的影响,过多则活性剂成分少,容量低;太少则导电性

差,电池容易产生极化;导电剂的粒度和分散程度对电池的性能也有重要影响。此外,混料前对导电剂进行一些表面

处理也能明显改善电池的循环性能。

关键词锂离子电池导电剂循环性能电导率

中图分类号:TM912.9文献标识码:A

EffectofConductiveAdditivesonthePerformanceofLithiumionBatteries

LIULu,DAIYongnian,YAOYaochun

(FacultyofMaterialsandMetallurgyEngineering,KunmingUniversityofScienceandTechnology,Kunming650093)

AbstractTheeffectofdifferentconductiveagentsoncyclebehavioroflithiumionbatteriesisreviewed.The

propertiesoflithiumionbatteriescanbeobviouslyimprovedbyusingcarbonblackastheconductivematerial,andit

willbebetterifusingcarbonfilament.Largecapacityandhighcycleefficiencycanbekeptathighchargeratebyadding

highelectricalconductivitymetal.Thecontentofconductiveadditivealsohasaninfluenceonthecycleperformance.

Theexcessivecontentofconductivematerialwillleadtolowcapacitybecauseofsmallactivematerial,onthecontrary,

thelesscontentwillbringthebadconductivityandpolarization.Thesizeanddispersionhaveasignificanteffectonthe

batteries.Inaddition,somesuracemodificationofconductivematerialscanimprovethecycleperformanceoflithiumion

batteriesbeforecommixing.

KeywordsLiionbat