2025年MCAT物理化学模拟测试.docxVIP

2025年MCAT物理化学模拟测试

考试时间：______分钟总分：______分姓名：______

1.Asystemundergoesaprocesswhereitsinternalenergyincreasesby150Janditabsorbs50Jofheatfromthesurroundings.Whatistheworkdonebythesystemiftheprocessisirreversible?

(A)200J

(B)100J

(C)-100J

(D)-200J

2.WhichofthefollowingstatementsistrueaccordingtotheSecondLawofThermodynamics?

(A)Theentropyofanisolatedsystemalwaysdecreasesovertime.

(B)Theentropyofaspontaneousprocessalwaysincreases.

(C)Theentropyofaperfectcrystalatabsolutezeroiszero.

(D)Allirreversibleprocessesarealsospontaneous.

3.Foraspontaneouschangeatconstanttemperatureandpressure,whichthermodynamicquantitymustbeminimized?

(A)InternalEnergy(U)

(B)Enthalpy(H)

(C)Entropy(S)

(D)GibbsFreeEnergy(G)

4.ThevantHoffequationrelatesthechangeinwhichquantitytotemperatureforareaction?

(A)Enthalpy(ΔH)

(B)Entropy(ΔS)

(C)GibbsFreeEnergy(ΔG)

(D)RateConstant(k)

5.ConsiderthereactionA→B.IftherateofformationofBismeasuredtobe0.025M/s,whatistherateofdisappearanceofA?

(A)0.025M/s

(B)-0.025M/s

(C)0.05M/s

(D)-0.05M/s

6.Areactionhasaratelawofrate=k[A]^2[B].IftheconcentrationofAisdoubledandtheconcentrationofBishalved,whathappenstothereactionrate?

(A)Itincreasesbyafactorof2.

(B)Itdecreasesbyafactorof2.

(C)Itincreasesbyafactorof4andthendecreasesbyafactorof2,resultinginnochange.

(D)Itincreasesbyafactorof4.

7.Activationenergyisbestdescribedas:

(A)Theminimumenergyrequiredforareactiontooccur.

(B)Thetotalenergyinputrequiredtostartareaction.

(C)Theenergyreleasedwhenproductsareformedfromreactants.

(D)Theenergybarrierthatmustbeovercomeforreactantstoconvertintoproducts.

8.Whichstatementistruea