物理化学双语教学：化学平衡与反应进程.pptx

Chapter6Chemicalequilibrium

MotivationQuestion:Canreactantsreactcompletelyinareaction?Why?

6-1Directionandlimitofchemicalreactions1.ReactionprogressξaA+bB=gG+hHξ=0ab00ξ(1-ξ)a(1-ξ)bgξhξDefinereactionprogressξ----thedegreetowhichareactionperforms(0ξ1).nA=(1-ξ)a,dnA=-adξ,similarly,dnB=-bdξ,dnG=gdξ,dnH=hdξSodni=νidξ(νi:reactioncoefficient;νi0,products;νi0,reactants)

Foraponentclosedsystem,ThefinallimitforareactionistoattaintheequilibriumandG