热力学可逆电池平衡常数计算.pptx

10-8Thermodynamicsofreversiblecell2004(c)DaleCarnegieAssociates,Inc.1.Calculationonequilibriumconstant

MotivationQuestion:Isthereanythermaleffectwhenagalvaniccellisworking?

a.(ΔrG)T,P=-Wf=-nEFb.Whenallthecompositionsthattakepartinthereactionareinthestandardstates,ΔrGm=-ZEFTogetherwith,ΔrGm=-RTlnKaThatgains,E=lnKaKa=exp()

2、RepresentationoftheelectromotiveforceGeneralreactionofcell:cC+dD=gG+hHFromthethermodynamicequationofthereaction,