计算氧化还原反应平衡常数通用步骤及实例.pptxVIP

3.ComputetheequilibriumconstantforOxi-redreactionGeneralprocedures:Designagalvaniccellaccordingtotheoxidation-reductionreaction.Consulttheappendixtogetthestandardelectrodepotentialsforthepositiveandthenegativeelectrodes.Calculatethestandardelectromotiveforce.Calculatetheequilibriumconstantusingthestandardelectromotiveforce.

Example:CalculateKaforthefollowingreaction.2Hg(l)+2Fe3+(m)=Hg22+(m”)+2Fe2+(m’)Negative:2Hg-2e→Hg22+(m”)Positive:2Fe3+(m)+2e=2Fe2+(m’)

4.DeterminationofPHa.Withhyd