储氢材料12-Hydrogen Storage materials.PPT

3) Single column pressure swing Steps: open 1# and 2# valve (P2 absorbed, D2 exit); close 1# and 2# valve; heat up column; open 3# (P2 exit). Ⅱ. Hydride hydrogen isotope separation Tel: 0571- 8795 1152 Email: lxchen@zju.edu.cn Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Hydride Hydrogen Separation Recovery and Hydride Hydrogen Isotope Separation Lecture XI 1.1 Background Recovery of waste H2 is beneficial to national economy I . Hydride Hydrogen Separation Recovery (2) Hydrogen is now mainly produced from fossil fuel; USA － natural gas; China Europe － coal. (1) Hydrogen is an important industrial fuel stock, also a good energy carrier; (3) In developing countries, H2 as a by-product gas is normally wasted. Industrial by-product H2 sources: a) Chloro-alkaline industry (氯碱工业); b) Ammonia fertilizer; NH3, (NH4)2SO4 c) Petroleum refining; d) Methanol (甲醇). I . Hydride Hydrogen Separation Recovery For example: Chloro-alkaline industry (氯碱工业) For 1 kg NaOH → 0.25 Nm3 H2 obtained In China, 3300000 t/yr NaOH → 820×106 Nm3/yr H2 I . Hydride Hydrogen Separation Recovery 1.2 Comparison of four existing separation techniques 1) Cryogenic separation (深冷分离) by condensation of non-hydrogen components Liquid N2 temperature ：－172℃; Purity ： 99 ~ 99.99%; Demerits：－ high energy consumption; － previous removal of CO2, H2O, H2S. I . Hydride Hydrogen Separation Recovery 2) Pressure Swing Absorption (P.S.A. 变压吸附) Use molecular sieve (分子筛). Merits: constant temperature operation; no pretreatment required; quite flexible; easy for automation. Demerits: I . Hydride Hydrogen Separation Recovery low purity － 99 ~ 99.9%; low percent of recovery. 3) Diffusion through diaphragms (膜分离) I . Hydride Hydrogen Separation Recovery (1) Pd