Pechini法合成尖晶石LiCoxMn2xO4及其结构表征.pdf

Sichuan Nonferrous Metals 25 Pechini 法合成尖晶石L iCo M n O x 2- x 4 及其结构表征 沈俊 陶菲 田从学 张昭 ( , 6 10065) : 采用Pechini 法制备纯尖晶石锰酸锂 L iM n O 和掺钴锰酸锂 L iCo M n O , 2 4 x 2 - x 4 结合化学分析和X 射线 射分析对产物进行表征实验结果表明, Pechini 法 易于制备纳米晶粒度的尖晶石锰酸锂和掺钴尖晶石锰酸锂煅烧温度为 800 , 在空气中延长煅烧时间可提高锰的价态, 得到富氧尖晶石掺钴锰酸锂 比纯锰酸锂有更好的结晶度和更稳定的尖晶石结构按照~ 8% 原料配比掺入 Co, 根据ED S 分析, 产物的化学计量式可表示为L iCo0. 14 M n1. 86 O4 : Pechini Synthesis of LiCo Mn O by Pechini Process and x 2- x 4 Its Structure Characterization Shen Jun , T ao Fei, T ian Congxue, Zh ang Zhao ( Coll eg e of Chem ical Engi neer ing , S ich uan Univ ers ity , Cheng d u S ich uan 6 10065, Chi na) Abstract: Pure lit hium manganese ox ide spinel LiMn2 O2 and cobalt - dop ed lit hium mang anese oxide LiCo Mn O w ere synt hesized by Pechini process. T he prepared samples w ere characterized by bot h t he x 2- x 4 chemical analysis and XR D t echnique. T he exp erimental results show t hat it is easy t o prep are nano- crys- t alline sp inel LiMn O and L iCo M n O by Pechini process. T he spinel w ith Mn ions in a higher ox idat ion 2 4 x 2 - x 4 st ate and oxyg en - rich can be obt ained b ased on a longer calcinat ion time at 800 under air . T he crys- t allinity of t he cob alt - do