组合捕收剂对黑钨矿疏水行为的影响研究.pdfVIP

组合捕收剂对黑钨矿疏水行为的影响研究 韩兆元，王国生，高玉德，徐晓萍 广州有色金属研究院，广州，510651 摘 要：试验考查了四种具有代表性的螯合捕收剂 GYB 及脂肪酸类捕收剂NaOL 、HPC、 731 及其组合使用对黑钨矿单矿物的浮选作用规律，结果表明，螯合剂GYB 与脂肪酸类捕 收剂NaOL 、731、HPC 的组合使用，增强了对黑钨矿的捕收能力，组合捕收剂对黑钨矿的 捕收能力强弱依次为：GYB+731 ＞ GYB+ HPC＞ GYB+NaOL，当GYB ：HPC：731=1 ：6： 3 时为最佳，使得黑钨矿浮选区间变宽，回收率增高。通过黑钨矿表面润湿性测试、疏水聚 团行为研究，探讨了组合捕收剂对黑钨矿疏水行为的影响。黑钨矿表面疏水性测试结果表明： 经组合捕收剂作用后，黑钨矿表面接触角增大，疏水性增强。黑钨矿泡沫产品的偏光显微镜 照片显示，经组合捕收剂作用后，黑钨矿疏水聚团更大、更紧密，易形成疏水聚团。 关键词：组合捕收剂，黑钨矿，疏水行为 InfluenceResearch onWolframiteHydrophobicBehavior By Combination Collectors HAN Zhao-yuan,WANG Guo-sheng,Gao Yu-de, Xu Xiao-ping Guangzhou Research Institute of Non-ferrous Metals,Guangzhou510651, ABSTRACT: The action law of wolframite as functions of four collectors and combination collectors which was chelating collector GYB and Fatty acid collector NaOL, HPC,731 was investigated by flotation experiments of pure mineral. Results showed that The collecting capability to wolframite was enhanced with the combination of chelating collector GYB and fatty acids collectors NaOL,HPC and 731.Intensity sequence of collecting capability was: GYB+731 ＞ GYB+HPC＞ GYB+NaOL.When GYB:HPC:731= 1:6:3, the best performance was gained and the flotation pH interval of wolframite was extended with the recovery increased.Influence research on w olframite hydrophobic behavior by combination collectors was disscussed as functions of surface wettability measurements and hydrophobic aggregation behavior. Results of surface hydrophobic properties measurement of wolframite showed that the contact angle of wolframite increased with the enhancement of surface hydrophobicity. Hydrophobic aggregation microscopical photos of froth product showed that the aggregation was bigger and tighter when acted by combined colle