海底沉积物层内CO2泄漏渗流与水合耦合规律研究.docVIP

  海底沉积物层内 CO2 泄漏渗流与水合耦合 规律研究# * 5 10 15 20 25 30 35 40  摘要：CO2 海底沉积物层封存被认为是缓解全球气候变化的有效途径。本文将 Darcy 定律与 水合物生成动力学方程通过质量守恒方程耦合，构建了描述海底沉积物层多孔介质中 CO2 泄漏渗流与水合物生成相互影响的动态演化数学模型，系统研究了不同温度下多孔介质体系 中 CO2 水合物饱和度随时间和空间的变化规律，以及 CO2 水合物生成对海底沉积物层渗流 特性参数的动态影响。模拟结果表明：在海底沉积物层水合区的泄漏口处，CO2 水合物生成 较为迅速，15 年时间内，由于 CO2 水合物生成、生长和积聚，导致近泄漏口处渗透率减小 近两个数量级，由初始值 1.0e-12m2减小到 6.5e-14m2，有效孔隙度由初始值 0.3减小到 0.2095， 降幅达 30%，形成了超低渗透的“CO2 水合物盖层”；海底沉积物层水合区温度越低，CO2 水 合物饱和度越低，有更多的游离 CO2 渗流泄漏入远场，当沉积物层温度为 281K 左右时，远 场处受泄漏影响最小，CO2 饱和度最低。 关键词：工程热物理；CO2（二氧化碳）；泄漏；渗流；水合物；海底沉积物层 中图分类号：X701;TE122.2+1 Research on the law of CO2 leakage and seepage coupled with hydration in sub-sea sediments CAO Zheng, LEI Xiao, CHEN Shitong, YANG Fusheng, DENG Jianqiang (School of Chemical Engineering and Technology, Xi’an Jiaotong University, Xi’an 710049) Abstract: CO2 sub-sea sediments disposal is considered to be an effective method to mitigate global warming. In this paper, A mathematical model describing the influence of hydrate formation upon CO2 leakage and seepage was constructed based on the Darcy’s Law and kinetics of hydrate formation, and we systematically studied the effect of hydrate formation on CO2 seepage in porous media and the dynamic evolution of sub-sea sediments’ characteristic parameters under different temperatures. The results show as: CO2 hydrate formed rapidly at the leakage outlet, For 15 years, CO2 hydrate formed, grew, and accumulated near the leakage outlet which led to the two- order-magnitude decrease of the sediments permeability, from the initial value 1.0e-12m2 to 6.5e-14m2. The effective porosity had a deep drop of 30%, from the initial value 0.3 to 0.2095 as an ultra-low-permeability CO2 hydrate cover layer formed. A lower temperature makes the saturation of CO2 hydrate smaller near the leakage outlet. The influence of leakage on the far field was relative small and made CO2 saturation the lowest at a temperature of 281K. Keywords: Engineering Thermophysics; CO2 (Carbon Dioxide); Leakage; Seep