磺化碳纳米管_聚氨酯光响应复合材料.doc

  磺化碳纳米管/聚氨酯光响应复合材料# 郭海强1,2，冯奕钰1,2，封伟1,2** （1. 天津大学材料科学与工程学院，天津 300072； 5 10 2. 天津市材料复合与功能化重点实验室，天津 300072） 摘要：首先将碳纳米管进行酸化和磺化两步处理，制备了磺化碳纳米管（CNT-SO3H），选 用聚氨酯（PU）为基体材料，用溶液共混法制备磺化碳纳米管/聚氨酯（CNT-SO3H/PU）复 合材料，并用扫描电镜（SEM）、氙灯、万能拉力机分别对复合材料的的微观形貌、光响应 性和力学性能进行了表征。CNT-SO3H 能均匀的分散在 PU 中，当 CNT-SO3H 含量为 2%时， 复合材料的光响应形变恢复率高达 84.21%，同时其力学性能也有提高，杨氏模量提高到 25.58 MPa。研究表明该复合材料具有光响应性和良好的力学性能，可应用在光响应驱动器 领域，实现光能到热能再到机械能转化的过程。 关键词：复合材料；磺化碳纳米管；聚氨酯；光响应；形状记忆材料 中图分类号：TB 332 文献标识码：A 15 Sulfonated Carbon nanotubes / Polyurethane light responsive composites Guo Haiqiang1,2, Feng Yiyu1,2, Feng Wei1,2 (1. Department of Materials Science and Engineering, Tianjin University, TianJin 300072; 20 25 30 35 40 2. Tianjin Key Laboratory of Composite and Functional Materials, TianJin 300072) Abstract: After acidification and sulfonation, the sulfonated carbon nanotubes(CNT-SO3H) were prepared firstly. Polyurethane was choosed as matrix material. Then sulfonated carbon nanotubes/polyurethane (CNT-SO3H/PU) composites were prepared by solution mixing method. The morphology, light responsiveness and mechanical properties were characterized by the scanning electron microscopy (SEM), xenon lamp and universal tensile machine, respectively. CNT-SO3H can disperse in PU uniformly, when the concentration of CNT-SO3H is 2%, the deformation recovery rate of light responsiveness is as high as 84.21% and its mechanical properties are also improved, the Youngs modulus increases to 25.58 MPa. The composites with light responsiveness and good mechanical properties can be applied in the field of light actuator to achieve the conversion process of light to heat and then to mechanical energy. Keywords: composite materials; sulfonated carbon nanotubes; polyurethane; light responsiveness; shape memory materials 0 引言 形状记忆高分子(SMP)是指具有初始形状的制品经形变固定后，通过外界条件的刺激， 又可使其恢复到原始形状的一类高分子材料。根据实现记忆功能的外界条件的不同，SMP 可以分为热致 SMP[1]、光致 SMP[2]、电致 SMP[3]、化学致 SMP[4]等。其中光致 SMP 因利用 了光能特有的远程可控性、瞬时性、环保性等优异的特性受到了较多的关注，光致 SMP 大 致可以分为两类[5]: 一是基于光响应分子的可逆光