现代长江主要支流与干流沉积物的REE组成.docVIP

  现代长江主要支流与干流沉积物的 REE 组 成# 杨守业1，王中波2* 5 10 15 20 25 30 35 40 45 （1. 同济大学海洋地质国家重点实验室,上海 200092； 2. 同济大学海洋与地球科学学院，上海 200092） 摘要：系统采集了长江主要支流与干流从上游到下游不同地区的河漫滩沉积物样品，运用 1M 盐酸淋滤处理比较研究稀土元素（REE）在不同相态中的组成特征。研究揭示，长江沉 积物中 REE 主要赋存于酸不溶相中，约占总含量的 70%左右。不同稀土元素的酸提取效率 不同，酸溶相明显富集稀土元素，主要受磷灰石等磷酸盐矿物和部分 Fe-Mn 氧化物矿物控 制。主要赋存于粘土矿物中的不同轻稀土元素在酸溶相中百分比接近，而富重稀土元素的重 矿物可以明显影响 REE 在不同相态中的组成和不同地区河流沉积物中 REE 的配分特征。长 江支流沉积物的 REE 组成变化大于干流，流域源岩组成差异是控制 REE 组成的基本因素， 但干流和支流沉积物全样与酸不溶相的 REE 配分模式基本类似，反映了各自流域风化上陆 壳的平均组成。尽管一些支流对邻近干流沉积物的 REE 组成贡献较大，但总体上干流样品 代表了不同支流水系沉积物的混合，尤其是下游近河口地区细粒级沉积物样品的酸不溶组分 可以代表长江入海颗粒物的平均 REE 组成，用于示踪判别东部边缘海长江沉积物的源汇过 程。 关键词：元素地球化学；长江；沉积物；稀土元素；控制因素；相态 Rare Earth elemental Compositions in the Sediments from the Major Tributaries and Main Stream of the Changjiang River Yang Shouye1, Wang Zhongbo2 (1. State Key Laboratory of Marine Geology, Tongji University，Shanghai 200092; 2. School of Ocean and Earth Science, Shanghai 200092) Abstract: The floodplain sediments were systematically collected from the major tributaries and mainstream of the Changjiang River in order to more convincingly investigate the compositions of rare earth elements (REEs). In this study, 1M HCl was used to separate the acid-leachable and residual fractions of REE in bulk samples. The analytic results suggest that REE is primarily enriched in the residual fraction, with its proportion up to 70% in the bulk concentration. Different REEs show variable leaching proportions and the leached fraction is relatively concentrated in middle REEs, which are sourced predominantly from the dissolution of phosphate minerals such as apatite and partly from Fe-Mn oxide minerals. Light REEs primarily reside in clay minerals and exhibit similar leaching proportions, whereas heavy REEs are generally concentrated in some heavy minerals demonstrate regular leaching proportions. The HREE-enriched heavy minerals can considerably influence the REE compositions between different fractions of the sediments from different tributaries. Overall, the