H3BO3和SiO2对CaTiO3：Pr3+长余辉发光性能的影响毕业论文.doc

本科毕业论文 题 目： H3BO3和SiO2对CaTiO3：Pr3+ 长余辉发光性能的影响 河北科技师范学院本科毕业论文（设计） PAGE II 摘 要 PAGE I 摘 要 稀土离子镨掺杂的碱土金属钛酸盐是一类化学性能稳定、色纯度高的红色长余辉发光材料，其余辉呈慢衰减的特性。自1997年新型发光材料CaTiO3：Pr3+应用到显示领域以来，Pr3+掺杂碱土金属钛酸盐（M=Ca、Sr、Ba）作为一种极具潜力的氧化基发光材料引起人们极大的关注。Pr3+掺杂碱土金属钛酸盐（M=Ca、Sr、Ba）发射纯正红光，它是色坐标为x=0.680、y=0.311的钙钛矿结构。CaTiO3：Pr3+的激发光谱为一宽带峰，峰值在324nm，属于Pr3+的3H4→4f5d跃迁；其发射峰呈锐线状，发射峰在614nm左右，对应于Pr3+的1D2→3H4转换。 本文旨在通过加入H3BO3和SiO2改良基质晶体环境，利用改进固相法制备出荧光性能优良的长余辉发光材料。实验发现，改进固相法能克服传统固相法的固有缺陷，有着简单可靠的技术优势。H3BO3的加入量为30%，物相组成为CaTi0.7Si0.3O3：0.05Pr3+时发光效果最佳。 关键词：CaTiO3:Pr3+；TiO2；SiO2；超声分散技术 Abstract Rare earth praseodymium doped calcium titanate persistent phosphor is chemically and hermally stable complex oxide, which is known for several years. MTiO3:Pr3+(M=Ca,Sr,Ba) phosphors have taken interests as a kind of the compellent oxide-based phosphors since CaTiO3:Pr3+ is developed as a newred phosphor for field emission display in 1997. It is proved that MTiO3:Pr3+ (M=Ca,Sr,Ba) phosphors have perovskite structure and high quality for red emission with chromaticity coordinates at x=0.680 and y=0.311. Among them, CaTiO3:Pr3+ phosphor is an example of oxide phosphors for which the excitation peak at the wavelength of 325nm corresponds to the 4f5d states of Pr3+, the single red emission peak at the wavelength of 614 nm is from 1D2 to 3H4 transition of Pr3+. This paper aims at improving crystal environment by the addition of H3BO3 and SiO2, and preparing long afterglow fluorescent material with excellent performance by improved solid state method. It was found that improved solid phase method can overcome the shortcomings of traditional solid state method, with a simple and reliable technical advantages. It got best glow in the addition of 30% H3BO3, phase composition at CaTi0.7Si0.3O3:0.05Pr3+. Keywords: CaTiO3:Pr3+; TiO2; SiO2; Assisted Ultrasonic Dispersal Technique PAGE IV 目 录 目 录 TOC \o 1-3 \h \z \u TOC \o 1-3 \h \z \u HYPERLINK \l _Toc290283810 摘 要 I HYPERLINK \l _Toc290283811 Abstract I