【论文】基于淀粉的纳米银的绿色微波合成法.pdfVIP

毕业设计（论文）中文摘要 本论文首次提出基于淀粉的绿色微波法合成纳米银的新工艺。在微波促进下， 淀粉水解生成还原糖，再进一步与硝酸银作用生成纳米级的银胶。本工艺中淀粉 既提供银胶合成中所需的还原剂，又充当生成的纳米银的保护剂，所得纳米银胶 具有良好的稳定性，并可以广泛应用于分析化学、物理化学领域。实验发现：纳 米银生长随淀粉浓度增大而线性增加；淀粉浓度超过 0.2﹪时，淀粉浓度的改变 对纳米银粒子的粒径分布和粒子大小没有明显的影响，且所得银胶的稳定性降低。 -4 硝酸银浓度较低时（7.5×10 mol/l），纳米银的形成速度随硝酸银浓度的增长而 线性增加，但纳米银的形成速度最终取决于溶液中水解产生醛糖的速度；硝酸银 浓度的改变对生成的纳米银的粒径以及粒径分布没有明显的影响。微波功率越高， 纳米银形成速度越小；高功率下形成的纳米银粒径分布较窄，粒子更加均一规整， 实验推测微波可能对纳米银的晶体化过程有很好的促进作用。 关键词 淀粉 纳米银 绿色合成 微波法 毕业设计（论文）外文摘要 Title Green Microwave Synthesis of Sliver Nanoparticles Based on Starch Abstract The new process of green microwave synthesis of nanoparticles based on starch is advanced for the first time in the text. Under the promotion of microwave synthesis of microwave, the starch hydrolyzes into reducing sugar, which makes chemical action with sliver nitrate into sliver nanoparticles. In this methodology starch not only provides reducing agent needed in the synthesis of sliver sol, but also be used as protective agent in the creation of sliver nanoparticles, which has nice stability and is widely used in the fields of analytical chemistry and physical chemistry. Experiment indicates that the growth of sliver nanoparticles increases linearly as the accretion starch concentration. when the concentration of starch larger than 2%, altering the starch concentration has no obvious impact on the grain path and the particle dimension of sliver nanoparticles particle, and also the stability of the gained sliver sol will bring down. When the concentration of sliver nitrate lower (＜7.5 × -4 10 mol/L), the spanning velocity of sliver nanoparticles increases li