NiCrAlY涂层对TiAl合金抗高温氧化的影响.docxVIP

TiAl合金表面NiCrAlY涂层的抗高温氧化性能周鹏，张平则，魏东博，魏祥飞，张扬 (南京航空航天大学材料科学与技术学院，南京210016)摘要：采用多弧离子镀技术在-TiAl合金表面制备了NiCrAlY涂层，用SEM、EDS和XRD 等分析了涂层在高温氧化前后的形貌、结构和物相组成，用恒温氧化方法测试了涂层与基体的氧化动力学曲线。结果表明：涂层在高温下可形成保护性氧化膜，与TiAl合金相比，氧化增重明显降低，抗氧化性能显著提升；但在850℃和950℃氧化时，Ni、Ti元素发生互扩散，850℃时，涂层与基体之间形成了扩散带和齿状TiNi相，950℃时，互扩散现象加剧，涂层表面生成了TiO2，涂层与基体界面处形成了kirkendall孔洞，加速了氧化膜的破裂，对提高抗高温氧化性能不利。关键字：γ-TiAl合金；多弧离子镀技术；NiCrAlY涂层；高温氧化中图分类号：TG174.445文献标志码：AEFFECT OF NiCrAlY COATINGS ON OXIDATION RESISTANCE OF TiAl INTERMETALLICSZHOUPeng, ZHANGPing-Ze,WEIDong-Bo,WEIXiang-Fei,ZHANGYang（College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China）ABSTRACT:A NiCrAlY coating was deposited on γ-TiAl alloys by multi-arc ion plating (MAIP). The morphology, microstructure and phase composition of coating were investigated by scanning electron microscopy (SEM),energy dispersive spectrometer (EDS) and X-raydiffraction (XRD).Oxidation resultsindicated that the coating can form a protective oxide film at high temperature, compared with the TiAl alloy, weight increase was decreased obviously, which significantly improved the oxidation resistance of TiAl alloy;but at 850℃ and 950℃, Ni, Ti elementsproduceda counter-diffusion, then formed the diffusion zone anddentate TiNi phases between coating and matrix at 850℃.For 950℃the mutual diffusion phenomenon aggravated, generated TiO2on the surface, which caused the formation of Kirkendallporosity at the coating /substrate interface, accelerated the rupture of oxide film, it was adversedto improve the high temperature oxidation resistance.Keywords: γ-TiAl alloy；Multi arc ion plating technology；NiCrAlY coating；High temperature oxidation0．引言TiAl基合金具有低密度、高比强度和比弹性模量的特点，同时还有良好的高温强度、刚度以及良好的高温蠕变及高温疲劳性能等优点，是极具应用前景的新型轻质高温结构材料。然而TiAl合金存在两个使其应用受到限制的主要问题，一是室温下的脆性，二是高温下（800℃以上）的抗氧化性能不足。随着对TiAl合金各种强韧化措施研究的不断深入，室温脆性和强度差等阻碍TiAl合金实用化的问题逐步得到了解决。因此进一步提高TiAl合金的抗高温氧化能力就成了急待解决的关键问题[1-5]。目前，材料工作者主要通过两种方式来改善TiAl合金的高温抗氧化性能：一是整体合金化，即通过添加合金元素以提高TiAl合金的高温氧化性能；二是通过表