纳米级Co3O4热扩散法制备Fe-Co合金层及其耐腐蚀性能研究.docVIP

低碳钢表面Fe-合金的热扩渗制备及腐蚀电化学研究盛敏奇万康a许继芳吕凯a (a 苏州大学 沙钢钢铁学院 苏州 215021) (b 上海大学 上海市现代冶金与材料制备重点实验室 上海 200072) 利用热扩渗方式，以Co3O4纳米粉体源，在低碳钢表面制备了Fe-合金层。研究了处理温度对合金层表面状态和结构的影响，并在3.5.%NaCl溶液中对合金层进行了腐蚀电化学研究。结果表明：处理温度高于800℃可在低碳钢表面形成厚度＞25μm，表面含量＞2at.%，并与基底形成冶金结合的Fe-合金层，合金层为单一Fe固溶体相电化学分析表明通过在低碳钢表面制备Fe-合金层可以明显改善在3.5.%NaCl溶液中耐腐蚀性能。Fe-Co合金 TB304 Thermal Diffusion Preparation and Corrosion Electrochemical Research of the Fe-Co Alloy Coating on Surface of Mild Steel Sheng Minqia,b*, Wan Kang a, Zhong Qingdong b, Xu Jifanga , Lv Chenkaia a. Shagang School of Iron and Steel, Soochow University, Suzhou, Jiangsu, 215021, PR China b. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai, 200072, PR China ABSTRACT Fe-Co alloy coatings were prepared on the surface of mild steel by means of thermal diffusion, using nano-Co3O4 powder as the source of Co element. The effects of treatment temperature on surface state, structure and corrosion resistance of the Fe-Co alloy coatings were investigated. The results show that: when treatment temperature≥800℃, single Fe solid solution phase Fe-Co alloy coatings(＞25μm formed and surface Co content (atomic fraction) were higher than 20at.%, and the coating and the substrate was integrated to metallurgy structure. Electrochemical analysis show that: By mild steel surface preparation of Fe-Co alloy coating can significantly improve the corrosion resistance in the 3.5mass% NaCl solution. Keywords: mild?steel, Fe-Co?alloy coating, thermal?diffusion, corrosion,electrochemical 作者简介：盛敏奇，男，博士，讲师smqtg@ No No，新世纪优秀人才支持计划(No. NCET-07-0536) 引言 利用热扩渗在金属材料表面制备合金层方法在现有研究和工业应用中较为广泛[1-5]。对于低碳钢而言，用于热扩渗的合金元素除C、B等原子半径较小的非金属元素外[6,7]，金属元素一般主要为Zn、Al、Cr、V等[8-11]，元素涉及较少。元素在改善钢铁材料的耐腐蚀性方面作用显著弱酸性Fe-Co合金比Fe-Cr或Fe-Ni合金拥有更强的耐腐蚀性[12]。合金在，Fe离子沿晶界氧化层固态扩散控制的，而Co可影响这一扩散过程，使含Co的铁合金在[13]。将金属元素在钢铁材料表面进行固相热扩渗时，大多采用这些金属元素的单质粉末或这些元素的Fe合金粉末为基本渗剂，此外还需要添加不同化学物质，渗剂成分复杂，并且处理完成后残余渗剂容易在基材表面黏结。在本文中，将含有纳米氧化物粉体涂覆在低碳钢表面充当热扩渗过程中的渗剂，通过H2还原并辅以