纳米级银颗粒的制备方法.pdfVIP

2005 年 6 月 贵 金 属 Jun. 2005 第 26 卷第 2 期 Precious Metals Vol. 26, No. 2 纳米级银颗粒的制备方法 张昊然，李清彪* ，孙道华，凌雪萍，邓 旭，卢英华，何 宁 （厦门大学化学工程与生物工程系，福建厦门 361005 ） The Preparation of Silver Nanoparticles * ZHANG Haoran, LI Qingbiao , SUN Daohua, LING Xueping, DENG Xu, LU Yinghua, HE Ning （Department of Chemical and Biochemical Engineering, Xiamen University, Xiamen , Fujian 361005, China ） Abstract: The main applications of silver nanoparticles in industry were briefly reviewed in the present paper. The methods used for preparation of silver nanoparticles were summarized and compared. The physical and chemical methods are relatively mature but they have some shortcomings. The biological method is recently developed as a promising method because of its special advantages such as sufficient material sources, mild reaction conditions, good dispersion of nanoparticles as well as few chemical addictives and poisonous byproducts. The biological method for preparation of silver nanoparticles included two mechanisms, namely enzymatic catalysis mechanism and non-enzymatic reduction mechanism. The full understanding of two mechanisms would be necessary for developing it into a practical process to prepare silver nanoparticles. Keywords: Metal materials; Silver nanoparticles; Preparation; Bioreduction 摘 要：在简要介绍纳米银在各个工业领域应用的基础上，总结比较了各种制备纳米银颗 粒的方法。物理和化学方法的工艺技术都比较成熟，但也存在着一定的不足。新兴的生物 还原法因其具有微生物原料来源广，生物还原反应条件温和，产物纳米颗粒不易团聚，以 及过程加入的化学试剂和产生的有毒副产物少等特点而开始受到关注。微生物还原金属离 子有 2 种不同的机理：微生物的酶催化机理和非酶还原机理。对生物还原法原理的充分认 识是将该方法发展成为可实际应用的纳米银制备工艺的重要基础。 关键词：金属材料；纳米银；制备；生物还原 中图分类号：TG 146.3+2 文献标识码： A 文章编号：1004-0676(2005)02-0051-06 纳米级的单质银颗粒因其独特的