HD-8阳离子交换树脂微柱分离铜的研究及应用.docVIP

HD-8阳离子交换树脂微柱分离铜的方法研究 徐琼，蒋冬杰 东华理工大学化学生物与材料科学学院，江西抚州，344000 摘要: 采用静态法研究了HD-8阳离子交换树脂吸附铜的吸附速率、吸附温度、吸附量等性能，并用微柱增压排空法选择了分离富集铜的最佳条件，即0.1～0.5mol?L-1盐酸溶液介质中铜的吸附率在95%以上，柱上吸附的铜用3mol?L-1 盐酸溶液3mL可洗脱完全。通过试验，确定了交换柱对微量铜的富集限为2ug/200mL，富集倍数为67，用来分离测定鄱阳湖水中痕量铜，铜的加标回收率为96%～105%。 关键词: HD-8阳离子；交换树脂；分离；铜 Separation and investigation of Cu by micro-chromatographic column packed with HD-8 cation exchange resins Xu Qiong , Jiang Dongjie Department of Applied Chemistry, East China Institute of Technology, Fuzhou, Jiangxi，344000 Abstract: micro-chromatographic column packed with HD-8 cation exchange resins, presented in this study, was couple to a static method for the separation and determination of Cu. Several operating parameters including adsorption rate, adsorption temperature, adsorption capacity on separation of Cu were investigated systematically with micro-column pre-exclusion of loading solution under pressure. The optimized parameters are found as follows: absorption rate of Cu in hydrochloric acid medium with a concentration in the range of 0.1-0.5 mol?L-1 was above 95%, adsorbed Cu on micro-column can be eluted completely with 3 mL of 3 mol?L-1 hydrochloride. Experimental data showed that enrichment limit of trace amount of Cu by micro-column was 2 ug/200mL, enrichment multiple was 67. The proposed method, applied to analyze Cu in water sample from Poyang lake, a recovery of standard addition between 96%-105%. Key words: HD-8 cation；exchange resins；separation；Cu μg铜于10mL比色管中，加2滴百里香酚酞指示剂，用氨水（1+1）调至出现蓝色，再用0.5mol?L-1盐酸溶液调至蓝色消失（PH为8.7～9.3）再加10%柠檬酸铵-氨水缓冲溶液1mL，2g?L-1二苯碳酰二肼溶液2mL，用水稀释至刻度，摇匀，放置10min于600nm波长处，用2cm比色皿，以试剂空白为参比测定吸光度。 1.2.5铜的原子吸收法则定 取一定量的铜标准溶液按试验方法上柱洗脱后，用水稀至10mL，摇匀，在原子吸收分光光度计测量吸光度。 1.2.6标准曲线的绘制 逐次移取消2，4，6，8，10μg铜标准溶液分别于10mL比色管中，按试验方法测定吸光度，绘制标准曲线。 图1 标准曲线 Fig1 standard curve 试验表明，铜的质量浓度在0～10μg/10mL范围内符合比尔定律，其线性相关系数为0.9998,线性回归方程为： Cu/ug=(A+0.0057)/0.04705 ε=1.5×104L·mol-1·cm-1 2 结果与讨论 2.1 HD-8阳离子交换树脂微柱分离富集铜的条件选择 2.1.1吸附酸度 移取10μg铜标准溶液，分别在不同的盐酸溶液介质中，流经交换柱，用10m