氧化皮对Q235钢腐蚀行为的影响.docVIP

氧化皮对Q235碳钢腐蚀行为的影响 谷荣坤，王鸿，宋义全 (内蒙古科技大学材料与冶金学院，内蒙古 包头 014010) [摘 要]利用750℃空气中恒温氧化和不同冷却方式在Q235碳钢表面制备了不同状态的氧化皮，利用SEM分析氧化皮形貌，并采用实验室加速腐蚀试验和电化学测量技术对比研究了裸表面钢和带有不同氧化皮的钢在0.5mol/L的NaCl溶液中的腐蚀行为。结果表明：表面氧化皮的存在改变了Q235的腐蚀行为，裸表面钢全面腐蚀，而带氧化皮在氧化皮脱落发生局部腐蚀；不同状态的氧化皮对Q235钢的腐蚀行为的影响也有所差异，空冷氧化皮表面致密完整，对基体保护性较好；水冷氧化皮缺陷较多，保护性较差。 [关键词] Q235碳钢；氧化皮状态；保护性；腐蚀；电化学 [中图分类号] TG174 [文献标识码] A Effects of Oxide Scales on Corrosion Behavior of the Q235 Carbon Steel Gu Rongkun, Wang Hong, Song Yiquan (Materials and Metallurgy School, Inner Mongolia University of Science and Technology, Baotou 014010) Abstract: Different structures scales were formed on the surface of Q235 carbon steel using isothermal temperature oxidation method at 750 ℃ in air and with different cooling methods. The micro-morphology of scales been inspected by SEM. Corrosion behaviors of the Q235 carbon steel with different oxide scales were investigated in 0.5 mol/L NaCl solution by accelerated immersion corrosion test and electrochemical technique. The results show that the oxide scale changed the corrosion behaviors of the Q235 carbon steel. The steel with oxide scale has the characteristics of localized corrosion. The steel with nude surface has the characteristics of general corrosion. The steels with different oxide scale had different corrosion characteristics. The oxide scale with air-cooled is dense and continuous, But the oxide scale with air-cooled with a lot of defects. The oxide scale with air-cooled exhibits more excellent corrosion resistance compared with that oxide scale with water-cooled. Keywords: Q235steel; oxide scale; Protective; corrosion; electrochemical 0 前言 钢铁在高温轧制过程中，其表层与空气接触形成一层氧化皮，由于轧制过程中加热温度以及冷却方式的不同，钢材表面的氧化皮组成及结构也千差万别[1，2]，氧化皮的存在改变了钢铁材料的腐蚀形态，表面结构良好、组织致密且与基体结合紧密的氧化皮可以很好地保护钢基体[3-5]，而缺陷较多的氧化皮则会加速钢铁材料的腐蚀[6]，因此研究不同状态氧化皮对钢铁材料腐蚀行为的影响具有现实和实际意义。本实验以大量应用于建筑及工程结构的Q235碳钢为研究对象，利用空冷和水冷两种冷却方式在其表面形成了不同结构的氧化皮，采用实验室加速腐蚀试验和电化学测量技术对比研究了裸表面钢和带有不同氧化皮的钢在NaCl溶液中的腐蚀行为，揭示氧化皮对Q235碳钢腐蚀行为的影响，为如何提高钢材耐蚀性能提供了参考依据。 1实验方法 实验材料用钢选用Q235碳钢，加工成