介孔氧化硅材料形貌的研究进展AdvancesinMesoporousSilica.pdfVIP

化学通报 2004 年 第67 卷 w010 介孔氧化硅材料形貌的研究进展 * 党文修 韩书华 侯万国 许 军 闫 欣 (山东大学胶体与界面化学教育部重点实验室 济南 250100) 摘 要 综述了介孔氧化硅材料形貌的最新研究进展 归纳总结了球形 棒状 纤维 螺旋 中空管和放射外形等形貌的介孔氧化硅的合成方法 着重阐述了超分子折叠机理 几何匹配机理 特性区扰动机理以及缺陷作用机理等形貌形成机理 关键词 介孔氧化硅 形貌形成机理 模板 合成 Advances in Mesoporous Silica Morphologies * Dang Wenxiu, Han Shuhua, Hou Wanguo , Xu Jun, Yan Xin (Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, (Shandong University) Jinan 250100) Abstract A variety of morphologies of mesoporous silica, such as sphere, rod, fiber, helicoid, hollow tubule and other radial patterns, can be synthesized by using surfactants as templates in either alkaline or acid solution. The formation of particular morphology depends on the experimental conditions of synthesis, including surfactant, cosolvent, precursor, counterions, acidity, temperature and so on. Several morphogenesis mechanisms, such as supramolecule origami mechanism, geometric matching mechanism, singularity-fluctuation mechanism and defect effect mechanism, are proposed in recent years. The latest advances in the particular morphology of silica-based mesoporous materials are summarized in this paper. Key words Mesoporous silica, Morphogenesis mechanisms, Synthesis, Template 超分子模板法制备介孔氧化硅材料的研究始于 1990 年[1] 而真正引起广泛关注的是 1992 年Kresge [2]和Beck [3] 分别报道的以表面活性剂为模板剂在碱性条件下合成的高度有序且孔径均 一的介孔硅酸盐和硅铝酸盐的新方法 他们合成的 MCM-41S 介孔氧化硅材料具有规则有序的 [4] [5]