原位生长碳纳米管对炭 炭复合材料导热性能的影响.pdfVIP

第 18 卷第 3 期 中国有色金属学报 2008 年 3 月 Vol.18 No.3 The Chinese Journal of Nonferrous Metals Mar. 2008 文章编号：1004-0609(2008)03-0383-05 原位生长碳纳米管对炭/炭复合材料导热性能的影响 周建伟，廖寄乔，王占锋 ( 中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：以炭纤维表面原位生长有碳纳米管(Carbon nanotubes, CNTs)的针刺毡体作为前驱体制备出生长有 CNTs 的炭/炭复合材料，并与在同样工艺条件下通过致密化最终热处理得到的纯炭/炭复合材料进行对比。结果表明， 在密度几乎相同的情况下，生长有 CNTs 的炭/炭复合材料的室温 Z 轴热导率约为 11.10 W/(m·K)，几乎为纯炭/炭 复合材料的室温 Z 轴热导率(6.28 W/(m·K))的2 倍，其原因可能在于：CNTs 可以有效改善炭纤维和热解炭之间的 界面特性，明显减少炭/炭复合材料中纤维和热解炭界面处周裂纹的出现，还可以诱导热解炭形成一种拥有更高导 热率更易石墨化的粗糙结构。 关键词：碳纳米管；炭/炭复合材料；热导率；热解炭 中图分类号：TB 332 文献标识码：A Effect of in situ grown carbon nanotube on thermal conductivity of carbon/carbon composites ZHOU Jian-wei, LIAO Ji-qiao, WANG Zhan-feng (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Carbon nanotubes(CNTs)-grown carbon/carbon (C/C) composites which have CNTs in situ grown on carbon fibers of needled carbon fiber felts, and pure carbon/carbon composites were fabricated by the chemical vapor infiltration (CVI) method to investigate the effect of CNTs on room temperature Z direction thermal conductivity of C/C composites. Thermal conductivity of samples were tested by laser flash method. The results show that the room temperature Z direction thermal conductivity of CNTs-grown C/C composites is about 11.10 W/(m·K) which is generally 2 times that of pure C/C composites with nearly the same density. The reason is that the favorable effect of CNTs on room temperature Z direction thermal conductivity of C/C composites is achieved by bett