煤及其拔头半焦的燃烧反应特性研究.pdfVIP

第40卷 第5期 燃摇 料摇 化摇 学摇 学摇 报 Vol.40 No.5 2012年5月 Journal of Fuel Chemistry and Technology May2012 文章编号:0253鄄2409(2012)05鄄0513鄄06 煤及其拔头半焦的燃烧反应特性研究 于广锁,祝庆瑞,许慎启,霍摇 威,周志杰 (华东理工大学 煤气化教育部重点实验室,上海摇 200237) 摘摇 要:采用热天平研究了贵州褐煤、三江原煤及其拔头半焦的燃烧行为,考察了粒径和升温速率对样品着火点和燃烧稳定 性的影响。 减小样品的粒径可显著降低样品的着火点,改善样品的燃烧性能,在粒径 100 ~120 目和升温速率25 益/ min下, 样品的燃烧稳定性最好。 根据Coats鄄Redfern方法求解燃烧反应动力学参数。 燃烧反应动力学分析表明,三种样品的热天平 燃烧反应均为一级反应,并得到了实验样品的燃烧反应动力学参数,表观活化能E和指前因子A。 贵州褐煤的活化能为100.0 ~163.6kJ/ mol,三江原煤的活化能为73.4 ~161.2kJ/ mol,三江煤焦的活化能为68.3~178.1kJ/ mol。 关键词:粒径;燃烧;着火点;热重分析 中图分类号:TQ534摇 摇 文献标识码:A Combustion characteristics of coal and coal char from coal topping process YU Guang鄄suo,ZHU Qing鄄rui,XU Shen鄄qi,HUO Wei,ZHOU Zhi鄄jie (Key Laboratory of Ministry of Educationfor Coal Gasification, East China University of Science and Technology,Shanghai摇 200237,China) Abstract:A systematic research on the combustion characteristics of Guizhou lignite, Sanjiang coal and SanjiangcharhadbeendoneusingSTA409CNetzh鄄thermogravimetricanalyzer. Theeffectsofparticlediameter and heating rate on maximum mass loss rate,ignition point and combustibility were analyzed. The decrease of particle diameter can reduce the ignition point and improve the combustibility. When particle size is 100 ~ 120 mesh and heatingrate is25益/ min,the combustibility of samplesisthebest. The combustion reactionsare one鄄order reaction and kinetics parameters (activation energy E and frequency factor A) were obtained by the method of Coats鄄Redfern basing on experimental data. Activation energy of Guizhou lignite,Sanjiang coal and Sanjiang char are 100.0~163.6kJ/ mol,73.4 ~161.2kJ/ mol,68.3~178.1kJ/ mol. Key words:particle diameter;combustion;ignition point;thermogravimetric analysis