双端丙烯酰基聚醚硅油的制备及其改性聚丙烯酸酯性能.docVIP

  双端丙烯酰基聚醚硅油的制备及其改性聚 丙烯酸酯性能 李强1，吴明华1,2，孙晓芳1，高笑飞1** 5 10 15 20 25 30 35 40 45 （1. 浙江理工大学，先进纺织材料与制备技术教育部重点实验室，杭州 310018； 2. 浙江理工大学，生态染整技术教育部工程研究中心，杭州 310018） 摘要：采用丙烯酸和双端羟基封端聚醚硅油为原料，通过酯化反应制备了双端丙烯酰基聚醚 硅油，研究了催化剂用量、反应温度、反应时间、甲苯溶剂和阻聚剂用量等因素对酯化率的 影响，优化酯化反应条件，用 FTIR 和 1H-NMR 对产物的结构进行了表征；并将其应用于聚丙 烯酸酯乳液的制备，测定了改性聚丙烯酸酯乳液及其涂料印花性能。结果表明：双端丙烯酰 基聚醚硅油合成工艺优化条件为催化剂和溶剂用量分别为反应物总质量的 5%、70%，阻聚剂 用量为丙烯酸质量的 0.75%，反应温度为 110，反应时间 4h；FTIR 和 1H-NMR 谱图表明产 物结构为丙烯酸酯化聚醚硅油；将其用于聚丙烯酸酯改性，其改性聚丙烯酸酯胶膜的疏水性 变大，胶膜断裂强度略有下降，但断裂延伸率明显上升，断裂功略有增加；将改性聚丙烯酸 酯乳液应用于涂料印花，印花织物干、湿摩可达 4 级及以上，印花织物手感变柔软。 关键词：织化学与染整工程；丙烯酸；酯化反应；丙烯酰基聚醚硅油；涂料印花 中图分类号：TQ316.33+4 Synthesis of double terminated acryloyl-polyether silicon oil and property of its modified polyacrylate latex LI Qiang1, WU Minghua1,2, SUN Xiaofang1, GAO Xiaofei1 (1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology(Zhejiang Sci-Tech University),Ministry of Education, HangZhou 310018; 2. Engineering Research Center for Eco-Dyeing Finishing of Textiles,Ministry of Education(Zhejiang Sci-Tech University), HangZhou 310018) Abstract: A double terminated acryloyl-polyether silicon oil was prepared by esterification reaction with acrylic- acid and polyether silicon oil terminated by double hydroxyl as raw materials. The influences of reaction factors such as amuont of catalyst，reaction temperature and time，dosage of solvent and inhibitor on the esterification rate were investigated，the condition of esterification reaction was optimized, and the structure of product was characterized by FTIR and 1H-NMR, double terminated acryloyl-polyether silicon oil was applied in the preparation of silicon-modified polyacrylate latex for pigment printing and the properties of silicon-modified polyacrylate was studied. The results showed that the optimal esterification condition was that the amouts of catalyst and solvent were 5% and 70% of total reactant mass respectively, the dosage of inhibitor were 0.75% of the amouts of acrylic acid, reaction temperature was 110℃