一种新型铁氮光催化的制备和筛选.pdfVIP

2011年摇 第35卷摇 摇 摇 摇 摇 摇 中国石油大学学报(自然科学版)摇 摇 摇 摇 摇 摇 摇 摇 Vol.35摇 No.6 摇 第6期摇 摇 摇 摇 摇 摇 摇 摇 Journal of China University of Petroleum摇 摇 摇 摇 摇 摇 摇 摇 Dec.2011 摇 摇 文章编号:1673鄄5005(2011)06鄄0179鄄04 一种新型铁氮光催化剂的制备和筛选 耿春香,王志伟,张秀霞,赵朝成 (中国石油大学化学工程学院,山东青岛266555) 摘要:以8种树脂为载体、4种有机含氮化物为配体、硫酸亚铁为络合金属,制备一系列树脂负载型铁氮配合物作为 光催化降解多相催化剂,考察H O 对腈纶废水的光催化降解效果。 结果表明:催化剂D113树脂负载1,10 菲啰啉 2 2 2+ 的降解效果较好;每克树脂负载60 mmol 的有机配合离子、n(菲啰啉)/ n(Fe )=2颐1、有机配合离子pH值为3郾0 ~ 3郾5 时,催化剂的光催化降解性能较好,COD去除率约50%,并可重复使用。 关键词:铁氮配合物;负载;筛选;光催化剂;腈纶废水 中图分类号:TE992.2摇 摇 摇 文献标志码:A摇 摇 摇 doi:10.3969/ j.issn.1673鄄5005.2011.06.032 Preparation and selection of a new鄄type iron鄄nitrogen photocatalyst GENG Chun鄄xiang,WANGZhi鄄wei,ZHANG Xiu鄄xia,ZHAO Chao鄄cheng (College of Chemical Engineering in China University of Petroleum,Qingdao266555 ,China) Abstract:A series of iron鄄nitrogen load resin complexes as photocatalytic degradation catalysts were prepared based on eight kinds of resins as the carrier,four kinds of organic nitrogen compounds as ligands,ferrous sulfate as the metal com鄄 plex. The preparation factorsof the catalyst intreating acrylicfiberwastewaterwere investigated. Theresults show thatthe best catalyst is D113 and 1,10 phenanthroline. The optimal reaction condition is loading 60 mmol of organic complex in + one gram of resin. Thebestmolarratioofphenanthroline/ Fe is2颐1andthepHrangeis3-3.5. Thebest CODdegrada鄄 2 tion in the photocatalytic system reaches about50% and the chemical properties are stable and can be reused. Key words:iron nitrogen complex;loading;filtration;photocatalyst;acrylicfiber wastewater 摇 摇 利用羟基自由