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21 5 2011 5
Vol.21 No.5 The Chinese Journal of Nonferrous Metals May 2011
1004-0609(2011)05-1099-07
Ni/C
1, 2 1 1 1
, , ,
(1. 100190
2. 100012)
Ni/C 4 MPa
65%Ni/C
/
TB333 A
Effects of nucleation and growth of nickel on
coating uniformity of Ni/C composite particles
1, 2 1 1 1
CHEN Ye , HUANG Chuan-bing , DU Ling-Zhong , ZHANG Wei-Gang
(1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering,
Chinese Academy of Sciences, Beijing 100190, China;
2. Environmental Monitoring of China, Beijing 100012, China)
Abstract: The effects of different coating stages and partial pressures of hydrogen on the coating uniformity of spherical
Ni/C composite particles were studied by pressurized hydrogen reduction. The preparation condition and formation
mechanism of Ni/C particles with compact and smooth coatings were investigated. The results show that the ideal coating
effect is achieved when the initial pressure of hydrogen occupied 65% of 4MPa initial total pressure. Final coating
morphology of Ni/C particles is decided by dynamics of nucleation and growth processes of nickel crystal.
Heterogeneous nucleation process is favorable for producing uniform coating, while the homogeneous nucleation and
crystal growth processes make the coating uniformity worse
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