应用热解吸-热脱附-GC-MS分析糖类对烟草烟气影响.docVIP

离线热解-TD-GC-MS分析烟草中主要糖类对挥发性成分的影响 陈熠熠1，赵瑜2*，杨华武2，庹苏行2，朱卓越2，陈波1* （1湖南师范大学， 湖南 长沙 410081，2湖南中烟工业有限责任公司技术中心， 湖南 长沙410007 ） 摘 要:建立了离线热解-热脱附（TD）-气相色谱（GC）-质谱法（MS）分析烟草中挥发性成分的方法，并应用本方法分析烟草中几种主要糖类对烟草挥发性成分的影响。结果表明：（1）糖类在高温下裂解，主要生成呋喃类、酸类、酯类等，不同糖类的裂解产物有较明显差异。（2）随糖类的加入，烟草中各大类挥发性成分均明显增加。其中，加入蔗糖后，醛、酮类和含氮、硫杂环类增加显著；加入果糖后，各类化合物增加均较少，其中含氧杂环类百分含量几乎没有变化；加入葡萄糖后，醇、酚类和含氧杂环类增加明显。实验结果说明糖类物质在热解过程中不仅自身发生氧化还原反应，还与烟草中的成分发生了一系列化学反应，从而显著影响烟气的化学组成。 关键词:热脱附；气相色谱/质谱；糖类；烟草；热裂解；挥发性成分 Determination the effects of the major sugars in tobacco on volatile components by off-line Thermal pyrolysis-TD-GC-MS CHEN Yiyi1，ZHAOYu2*，YANG Huawu2，TUO Suxing2，ZHU Zhuoyue2，CHEN Bo1* (1．Hunan Normal University，Hunan，Changsha 410081；2 .Technology Center of China Tobacco Hunan Industrial Corporation， Hunan，Changsha 410007) Abstract: A novel method for the determination of volatile components in tobacco was established by using Pyrolysis-Thermal desorption-Gas chromatography/mass spectrometry， and then studying the effects of the major sugars in tobacco on volatile components. The results indicated that 1) Sugars pyrolysates were identified， mainly including furan derivatives， acids and esters， and the contents of pyrolysates were obviously different in sucrose， fructose and glucose. 2) Most of the volatile components in the tobacco which were added sugars were increased after pyrolysis. Sucrose has more influence on aldehydes， ketones， nitrogen heterocyclic and sulfur heterocyclic than others. Fructose has litter influence on aroma components， especially for oxygen heterocyclic. Glucose also has obvious influence on the contents of aroma components， especially for alcohols， phenols and oxygen heterocyclic. It is concluded that sugars in tobacco significantly contribute to the volatile components in tobacco smoking. Key words: Thermal desorption; Gas chromatography-mass spectrometry; Sugar; Tobacco; Pyrolysis; Volatile components 糖类是烟草中一类重要的化合物，其含量对烤烟品质有显著影响。在卷烟燃吸过程中，糖类不仅自身发生氧化、裂解反应，产生大量挥发性成分，还能与烟草中的其他组分发生化学反应，生成一系列影响卷烟品