有机硼π-共轭光电功能材料研究进展.pdfVIP

中国科技论文在线 有机硼π-共轭光电功能材料研究进展# 赵翠华，赵以红，林吉茂* （山东大学化学与化工学院，济南 250100） 5 摘要：由于硼元素所特有的一些性质，如硼原子空的p轨道与π-共轭体系的π*轨道间的 p π-π*共轭效应、与Lewis碱络合所表现出的强Lewis酸性以及为获得足够的动力学稳定性 在硼原子上所引入的大体积芳香取代基使之表现出的立体位阻效应等，将硼引入到π-共轭 体系可以赋予体系一些独特的光电性能，因此近年来含硼π-共轭材料引起了人们极大的研 究兴趣。这类材料已经显示出非常广阔的应用前景，可以用作非线性光学材料、双光子吸收 10 和发光材料、有机电致发光器件中的电子传输材料和发光材料以及化学传感器等。本文根据 π-共轭体系分子结构的不同，对有机硼π-共轭材料，包括硼取代基位于末端的线形π-共 轭体系、硼原子位于中心的星形π-共轭体系、硼原子位于主链的π-共轭聚合物体系、硼桥 联的并环π-共轭体系以及硼取代基位于侧链的π-共轭体系等的研究进展进行了综述，并进 一步对该领域的发展前景进行展望。 15 关键词：有机硼π-共轭材料；pπ-π*共轭效应；Lewis酸性；立体位阻效应 中图分类号：0627.3; 0649.5 Research Progress in the Optoelectronic Materials of Organoboron π-Conjugated Systems 20 Zhao Cuihua, Zhao Yihong, Lin Jimao (School of Chemistry and Chemical Engineering,Shandong University, JiNan 250100) Abstract: The boron-containing π-conjugated materials have attracted considerable research interest in recent years due to their unique optoelectronic properties, which stem from the characteristic features of boron element, such as the pπ-π* conjugation between the vacant p 25 orbital on the boron atom with π* orbital of the π-conjugated framework, the high Lewis acidity to coordinate with Lewis bases, as well as the steric bulk arising from the aryl substituent on the boron atom to get enough kinetic stability. It has been demonstrated that this kind of materials are applicable in a wide range of fields, such as nonlinear optics, two-photon absorption and emission materials, electron-transporting and emissive