剥离型聚丁二烯液体橡胶;有机粘土纳米复合凝胶制备条件的考察.pdfVIP

中国科技论文在线 剥离型聚丁二烯液体橡胶/有机粘土纳米复 合凝胶制备条件的考察# 陈铁红，朱建君，孙平川* 5 （南开大学化学学院，天津 300071 ） 摘要：本文采用 X 射线衍射分析方法, 以聚丁二烯液体橡胶/有机粘土复合凝胶为研究对象, 对剥离型端官能团液体橡胶/有机粘土纳米复合材料制备条件进行了探索。通过对制备方法、 有机改性剂烷基链长、粘土层间有机胺阳离子负载量、有机粘土含量的研究，以及液体聚丁 二烯橡胶端官能团的比较，得到在此实验条件下的理想制备条件：普通的搅拌条件下，有机 10 改性剂选择烷基链长为16 个碳原子以上的季铵盐，有机粘土的含量选择为10 wt ％。 关键词：粘土；复合凝胶；剥离型 Investigation of preparation conditions on exfoliated polybutadiene liquid rubber/organic clay composite gel 15 Chen Tiehong, Zhu Jianjun, Sun Pingchuan (College of Chemistry, Nankai University, Tianjin 300071) Abstract: The preparation conditions of liqiud rubber/organic clay nanocomposite of exfoliated terminal functional group was investigated in the system of polybutadiene liquid rubber/organic clay composite sel by using X-ray diffraction methods. By the investigation of preparation 20 methods, the alkyl length of organic modifier, the loading of organic amine cation between the clay layer, the content of organic clay, and the comparation of exfoliated terminal functional group of polybutadiene liquid rubber, the results indicated the ideal preparation conditions: under the ordinary stirring, choosing quaternary ammonium salt with a alkyl chain length at least sixteen carbon atoms as organic modifier, the loading of organic amine cation between the 25 montmorillonite layer was close to the content of montmorillonite, and the content of organic clay was 10 wt%. Key w