含氟硅油作为润滑油添加剂的摩擦学性能研究.pdfVIP

第31卷 第3期 摩 擦 学 学 报 Vol31 No3 20l1年 5月 Tribology May，2011 含氟硅油作为润滑油添加剂的摩擦学性能研究 冯 欣 (华北电力大学 能源动力与机械工程学院，北京 102206) 摘 要：用 SRV摩擦磨损试验机评价了2种含氟硅油在聚 烯烃基础油中作为添加剂的摩擦学性能，用扫描电子 显微镜(SEM)和x射线光电子能谱仪(xPs)观察并分析了磨斑表面形貌和主要元素的化学状态，探讨了含氟硅油 的摩擦化学机制．结果表明：含氟硅油具有优良的减摩和抗磨性能；含氟硅油在摩擦作用下发生分解，在摩擦副表面 生成的含氟的摩擦化学产物是提高摩擦副抗磨减摩性能的关键因素． 关键词 ：含氟硅油；摩擦 ；磨损；摩擦化学；润滑油添加剂 中图分类号：THI17．3 文献标志码：A 文章编号：1004—0595(2011)05—0205—05 TribologicalPropertiesofFluorosiliconeContaining OilsasLubricantAdditives FENG Xin (SchoolofEnergyPowerandMechanicalEngineering，NorthChinaElectricPowerUniversity，Beijing102206，China) Abstract：ThefrictionandwearoftwokindsoffluorosiliconeoilsaslubricantadditiveswereevaluatedonanOptimolSRV reciprocatingrfictionandweartesterbyusingAISI52100steeldiscagainstAISI52100steelballatappliedloadsof50and 200N，aslidingspeed of0．20m ／s．ThewearscarsizesofAISI52100 steeldiscsand AISI52100 steelbailswere measuredusinganopticalmicroscope．ThemorphologiesofthewornsurfacesoftheAISI52100steeldiscswereexamined usingascanningelectronmicroscope(SEM)．Inaddition，theelementalcompositionsandchemicalstatesofseveraltypical elementsonthewornSurfacesofthesteeldiscswereexaminedbymeansofX—rayphotoelectronspectroscopy(XPS)． Resultsindicatedthattheevaluatedtribo—pairunderlubricationofPAO baseoilusingfluorosiliconecontainingoilsas lubrieantadditivesexhibite~lhigherwear—resistanceandlowerstablerfictioncoemcientsthanthatinDurePAO baseoil． Thisispartlyattributedtotribophysicalandtribochemicalreactionbetweenthelubricantandtheslidingsurfaces． Keywords：fluorosilieoneoil，rfiction，wear，tribochemical，lubricantadditives 硅油是一类