合金改性激光表面改性工艺及性能研究与应用毕业论文.docVIP

激光表面改性工艺及性能研究及合金密度小，比强度高，具有良好的耐蚀性、疲劳抗力，广泛应用于航天航空国防、汽车、医疗等领域。然而，合金摩擦系数高、对粘着磨损和微动磨损非常敏感、耐磨性差及高温抗氧化性差等缺点，制约了它的应用。在保持合金固有性能优点的条件下，激光表面改性是从根本上解决合金表面性能较差这一缺陷的有效、经济、灵活且具有较强可设计性的方法之一。 本文运用CO激光，在Ti6A14V合金表面进行激光表面改性，直接在Ti6A14V合金表面制得了具有优异耐磨性能和抗高温氧化性能，并与Ti6A14V合金基体之间呈现牢固冶金结合的复合材料涂层。 首先，为确保激光表面改性的顺利进行，研制了激光表面改性专用的同轴保护送粉装置，并探索了适合该同轴保护送粉装置的工艺参数，获得较高的粉末利用率和较好的保护效果。 其次，设计了激光表面改性材料体系。根据Ti6A14 V合金和激光表面改性的特点，设计出激光熔覆Ni-Ni基合金梯度涂层、激光熔覆Mo-Ni基合金梯度涂层、激光表面原位生成Ti涂层和激光表面原位生成TiC+TiB:涂层四类材料体系。 再次，研制了激光表面改性工艺。分别研制出各种材料体系对应的激光工艺参数，制得激光表面改性层，着重研究了不同工艺参数对激光熔覆Ni-Ni基合金梯度涂层的影响，探索最佳工艺参数。对激光表面改性涂层进行了微观分析，从表面至基体测试了显微硬度，发现涂层组织呈快速凝固特征，硬度梯度明显，有效地改善了涂层的应力分布状况。 最后，研究了激光表面改性涂层的摩擦学性能和抗高温氧化性能。研究发现，激光表面改性能够大大地提高了Ti6A14V合金的耐磨性能和抗高温氧化性能。 :Ti6A14V钛合金激光表面改性微观组织硬度梯度耐磨性抗高温氧化性 Abstract Titanium alloys are used widely in aviation, national defence, automobile, medicine and other fields because of their advantages in lower density, excellent corrosion resistance, and good fatigue resistance etc. However, their high friction coefficient, high sensitivity to adhesive wear and fretting wear, as well as their weak resistance to wear and bad resistance to high temperature oxidation restricts the application of titanium alloys. Laser surface modification technique can change these surface defects of titanium alloys under the condition of keeping the virtues of titanium alloy substrate. For the reason, laser surface modification is one of effective, economic, appropriate and designable methods. In this paper, surfaces of Ti6A14V alloy were modified by CO2 laser. Special composite metallurgy coatings, which have excellent wear resistance and high temperature oxidation resistance, were obtained directly on the surfaces of Ti6A14V alloy. Furthermore, the coatings showed good metallic combination with the substrate of titanium alloy. In order to carry out the laser surface modification process successfully, a coaxial powder feed nozzle with gas protection was designed at first. Through investigations o