溶剂萃取分离地下强化抽出处理液中的污染物和表面活性剂.pdfVIP

中国环境科学 2014,34(4) ：912~916 China Environmental Science 溶剂萃取分离地下强化抽出处理液中的污染物和表面活性剂 * 李璐璐,赵勇胜,王贺飞,苏 燕,秦传玉 ,吴亚萍 (吉林大学地下水资源与环境教育部重点实验室,吉林 长春 130000) 摘要：以正己烷为萃取剂,SDS 和 Tween 80 为表面活性剂,苯和硝基苯为污染物,通过批次实验研究了萃取时间、油水比、表面活性剂及污 染物性质对二者分离效果的影响.结果表明,萃取时间为 2h 、油水比为 0.1 是萃取的最佳条件参数;正己烷对 Tween 80 和苯的分离效果较 SDS 好,且 Tween 80 浓度对分离效果影响不大;随着 SDS 浓度的升高,其与苯的分离效果先增大后减小,在 1.375CMC 时达到最佳分离效果; 正己烷对苯与 SDS 的分离效果较硝基苯好,且分离效果随着污染物浓度的升高而增大;苯和硝基苯共存时,其与 SDS 的分离存在竞争作用. 关键词：溶剂萃取；表面活性剂；分离效果；正己烷 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2014)04-0912-05 Solvent extraction for separating organic pollutants and surfactants in pumped groundwater during SEAR. LI * Lu-lu, ZHAO Yong-sheng, WANG He-fei, SU Yan, QIN Chuan-yu , WU Ya-ping (Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130000, China). China Environmental Science, 2014,34(4)：912~916 Abstract ：The subject investigated the effect of extraction time, oil/water ratio, surfactants nature and contaminant nature on separation effect, with n-hexane as extracting agent, benzene as the target pollutant, sodium dodecyl sulfate (SDS) and Tween 80as surfactants through batch experiments. The results showed that, the optimum condition parameter of extraction was 2h of extraction time and 0.1of oil water ratio. For n-hexane, the effect of separating Tween 80 and benzene was better than SDS and benzene. And Tween 80concentration had little effect on separation efficiency. The effect of separating benzene and SDS increased with the concentration of SDS firstly, then decreased with that of SDS, and at 1.375CMC reached the optimum separ